Activity and stability of thermally stable polyimide-supported Mo(VI) complexes for epoxidation of olefins

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Functional polyimides have been prepared in a bead form by non-aqueous suspension polycondensation. Molybdenum(VI) complex has been supported on a functional polyimide bead containing a triazole group and used as a catalyst in the liquid-phase epoxidation of olefins with tert-butylhydroperoxide (TBHP), as oxygen source. The polyimide-supported Mo catalyst was highly active and selective, and has been recycled 10 times with no detectable loss of Mo from the support. ? 2000 Elsevier Science B.V. All rights reserved.
Publisher
Elsevier BV
Issue Date
2000-01
Language
English
Citation

Studies in Surface Science and Catalysis, v.130, pp.1655 - 1660

ISSN
0167-2991
DOI
10.1016/S0167-2991(00)80438-3
URI
http://hdl.handle.net/10203/24179
Appears in Collection
CBE-Journal Papers(저널논문)
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