This paper deals with how the use of Polybenzimidazole (PBI) as a film coating over conventional composite designs could help improve the hypervelocity impact ballistic performance of the system. PBI coated composite samples were studied for resistance to Low Earth Orbit environment conditions like high vacuum, thermal cycling, Atomic Oxygen and Ultraviolet Radiation in a simulation facility. It was observed that the PBI coated composites reduced mass loss and surface erosion compared to the non-coated samples after LEO exposure. Hypervelocity impact experiments were conducted on the PBI coated composites for impact velocities between 2.5 to 3 km/s. The experiments showed that the PBI film coating significantly increased the energy absorption of the composite system. The effect of thickness increase as a result of the film application on energy absorption was also found to be negligible confirming the effectiveness of PBI coating as a hypervelocity shield.