Methoxy[meso-5,10,15,20-tetrakis-(2,6-difluorophenyl)porphyrinato]-iron(III), [Fe(TDFPP)(OCH3)]

Cited 4 time in webofscience Cited 0 time in scopus
  • Hit : 146
  • Download : 0
The crystal structure of the title compound, [Fe(C44H20F8N4)(CH3O)], has been determined. The Fe atom lies 0.485 (1) Angstrom out of the plane of the four N atoms to which it is coordinated and from the inversion centre at the origin of the unit cell. The methoxy group is axially coordinated to the Fe atom with OD Fe-N angles of 106.3 (2) and 102.4 (2)degrees, a C-O-Fe angle of 128.3 (5)degrees and an Fe-O distance of 1.788 (5) Angstrom. Difluorophenyl rings are tilted from the porphyrin (por) plane with torsion angles of -68.1 (6) and 77.7 (5)degrees across the two C-por -C-C-C-ar systems.
Publisher
MUNKSGAARD INT PUBL LTD
Issue Date
2001-05
Language
English
Article Type
Article
Citation

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, v.57, pp.556 - 557

ISSN
0108-2701
DOI
10.1107/S0108270101003006
URI
http://hdl.handle.net/10203/240346
Appears in Collection
CH-Journal Papers(저널논문)
Files in This Item
There are no files associated with this item.
This item is cited by other documents in WoS
⊙ Detail Information in WoSⓡ Click to see webofscience_button
⊙ Cited 4 items in WoS Click to see citing articles in records_button

qr_code

  • mendeley

    citeulike


rss_1.0 rss_2.0 atom_1.0