The present invention relates to a method for separation of gas constituents from a multicomponent gaseous mixture employing a hydrate promoter. The method for separation of gas constituents from a multicomponent gaseous mixture includes the steps of reacting an aqueous solution containing a hydrate promoter with a multicomponent gaseous mixture to form a gas hydrate condensed with the gas constituents of high gas hydrate forming power and dissociating a specific gas component from the gas hydrate. In accordance with the present invention, a specific gas component can be seperated from a multicomponent gaseous mixture under a pressure much lower than that of the prior art method, which makes possible its practical application in various industrial areas emitting exhaust gases.