DC Field | Value | Language |
---|---|---|
dc.contributor.author | Jin, MinKyu | ko |
dc.contributor.author | Oh, You-Kwan | ko |
dc.contributor.author | Chang, Yong Keun | ko |
dc.contributor.author | Choi, Minkee | ko |
dc.date.accessioned | 2017-09-25T05:13:13Z | - |
dc.date.available | 2017-09-25T05:13:13Z | - |
dc.date.created | 2017-08-10 | - |
dc.date.created | 2017-08-10 | - |
dc.date.issued | 2017-08 | - |
dc.identifier.citation | ACS SUSTAINABLE CHEMISTRY & ENGINEERING, v.5, no.8, pp.7240 - 7248 | - |
dc.identifier.issn | 2168-0485 | - |
dc.identifier.uri | http://hdl.handle.net/10203/226019 | - |
dc.description.abstract | Product distributions in bio-crude, aqueous phase, and solid residue were rigorously analyzed during the hydrothermal liquefaction (HTL) of Chlorella sp. KR1 in order to optimize utilization of energy and chemicals. A non-asphaltene (paraffinic) fraction in the bio-crude, which can be readily upgraded to high-quality fuels via a subsequent catalytic process, was mainly produced due to lipid extraction. Above 170 °C, lipid extraction was almost complete, and hence, the non-asphaltene content did not increase further with increasing temperature. Carbohydrates could be extracted, mainly as polysaccharides, in the aqueous phase at mild temperatures (<200 °C). At high temperatures (>200 °C), they decompose and react with proteins via the Maillard reaction to form asphaltene (polycyclic aromatics), which contains large amounts of heteroatoms such as N and S. Although high-temperature carbohydrate conversion could yield more bio-crude with high energy values, it dominantly contributed to formation of the asphaltene fraction, which is difficult to upgrade catalytically. As high-temperature HTL requires a large energy input, the recovery and utilization of intact carbohydrates and proteins at mild temperatures (<200 °C) appears to be more promising. Energy Return on Investment (EROI) analysis also showed that 170 °C is the optimum HTL temperature for maximizing the energy production. | - |
dc.language | English | - |
dc.publisher | ACS Publication | - |
dc.subject | BIO-CRUDE OIL | - |
dc.subject | BIODIESEL PRODUCTION | - |
dc.subject | MAILLARD REACTION | - |
dc.subject | THERMOCHEMICAL LIQUEFACTION | - |
dc.subject | ORGANIC-SOLVENTS | - |
dc.subject | HIGH-TEMPERATURE | - |
dc.subject | ALGAL BIOMASS | - |
dc.subject | LIPID-CONTENT | - |
dc.subject | FLOW REACTOR | - |
dc.subject | MICROALGAE | - |
dc.title | Optimum Utilization of Biochemical Components in Chlorella sp KR1 via Subcritical Hydrothermal Liquefaction | - |
dc.type | Article | - |
dc.identifier.wosid | 000407410900097 | - |
dc.identifier.scopusid | 2-s2.0-85026999001 | - |
dc.type.rims | ART | - |
dc.citation.volume | 5 | - |
dc.citation.issue | 8 | - |
dc.citation.beginningpage | 7240 | - |
dc.citation.endingpage | 7248 | - |
dc.citation.publicationname | ACS SUSTAINABLE CHEMISTRY & ENGINEERING | - |
dc.identifier.doi | 10.1021/acssuschemeng.7b01473 | - |
dc.contributor.localauthor | Chang, Yong Keun | - |
dc.contributor.localauthor | Choi, Minkee | - |
dc.contributor.nonIdAuthor | Oh, You-Kwan | - |
dc.description.isOpenAccess | N | - |
dc.type.journalArticle | Article | - |
dc.subject.keywordAuthor | Hydrothermal liquefaction | - |
dc.subject.keywordAuthor | Microalgae | - |
dc.subject.keywordAuthor | Carbohydrate | - |
dc.subject.keywordAuthor | Nutrient recycle | - |
dc.subject.keywordAuthor | Energy | - |
dc.subject.keywordPlus | BIO-CRUDE OIL | - |
dc.subject.keywordPlus | BIODIESEL PRODUCTION | - |
dc.subject.keywordPlus | MAILLARD REACTION | - |
dc.subject.keywordPlus | THERMOCHEMICAL LIQUEFACTION | - |
dc.subject.keywordPlus | ORGANIC-SOLVENTS | - |
dc.subject.keywordPlus | HIGH-TEMPERATURE | - |
dc.subject.keywordPlus | ALGAL BIOMASS | - |
dc.subject.keywordPlus | LIPID-CONTENT | - |
dc.subject.keywordPlus | FLOW REACTOR | - |
dc.subject.keywordPlus | MICROALGAE | - |
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