DC Field | Value | Language |
---|---|---|
dc.contributor.author | Kim, Kiseong | ko |
dc.contributor.author | Hyun, Jaeyong | ko |
dc.contributor.author | Kim, Jin | ko |
dc.contributor.author | Kim, Hyunwoo | ko |
dc.date.accessioned | 2017-08-08T06:47:05Z | - |
dc.date.available | 2017-08-08T06:47:05Z | - |
dc.date.created | 2017-08-07 | - |
dc.date.created | 2017-08-07 | - |
dc.date.created | 2017-08-07 | - |
dc.date.issued | 2017-07 | - |
dc.identifier.citation | ASIAN JOURNAL OF ORGANIC CHEMISTRY, v.6, no.7, pp.907 - 912 | - |
dc.identifier.issn | 2193-5807 | - |
dc.identifier.uri | http://hdl.handle.net/10203/225214 | - |
dc.description.abstract | A [(RhCp)-Cp-III*]-catalyzed directed C-H hydroxylation of 2-arylpyridines is described (Cp*=1,2,3,4,5-pentamethylcyclopenta-2,4-dienyl), in which the combination of [(RhCp*Cl-2)(2)]/AgF, PhI(OPiv)(2), and water is used an effective catalytic system. According to our mechanistic studies, including O-18-labeling experiments and X-ray crystallographic analysis of an intermediate Rh complex, we demonstrate that water and PhI(OPiv)(2) are required for Rh catalysis as the hydroxy source and the oxidant, respectively. | - |
dc.language | English | - |
dc.publisher | WILEY-V C H VERLAG GMBH | - |
dc.title | Water as a Hydroxy Source in a Rh-III-Catalyzed Directed C-H Hydroxylation of 2-Arylpyridines | - |
dc.type | Article | - |
dc.identifier.wosid | 000405725900019 | - |
dc.identifier.scopusid | 2-s2.0-85024384017 | - |
dc.type.rims | ART | - |
dc.citation.volume | 6 | - |
dc.citation.issue | 7 | - |
dc.citation.beginningpage | 907 | - |
dc.citation.endingpage | 912 | - |
dc.citation.publicationname | ASIAN JOURNAL OF ORGANIC CHEMISTRY | - |
dc.identifier.doi | 10.1002/ajoc.201700196 | - |
dc.contributor.localauthor | Kim, Hyunwoo | - |
dc.contributor.nonIdAuthor | Hyun, Jaeyong | - |
dc.description.isOpenAccess | N | - |
dc.type.journalArticle | Article | - |
dc.subject.keywordAuthor | C-H activation | - |
dc.subject.keywordAuthor | hydroxylation | - |
dc.subject.keywordAuthor | hypervalent compounds | - |
dc.subject.keywordAuthor | rhodium | - |
dc.subject.keywordAuthor | water | - |
dc.subject.keywordPlus | BOND ACTIVATION | - |
dc.subject.keywordPlus | ARENES | - |
dc.subject.keywordPlus | FUNCTIONALIZATIONS | - |
dc.subject.keywordPlus | OXYGENATION | - |
dc.subject.keywordPlus | OXIDANT | - |
dc.subject.keywordPlus | LIGAND | - |
dc.subject.keywordPlus | OLEDS | - |
dc.subject.keywordPlus | O-2 | - |
dc.subject.keywordPlus | IR | - |
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