Total Synthesis of (+/-)-Waihoensene

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The first total synthesis of waihoensene, a tetracyclic diterpene containing an angular triquinane and a six-membered ring, with four contiguous quaternary carbon atoms, was achieved through the tandem cycloaddition reaction of an allenyl diazo substrate containing a six-membered ring via trimethylenemethane (TMM) diyl intermediate.
Publisher
WILEY-V C H VERLAG GMBH
Issue Date
2017-07
Language
English
Article Type
Article
Citation

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, v.56, no.28, pp.8254 - 8257

ISSN
1433-7851
DOI
10.1002/anie.201704492
URI
http://hdl.handle.net/10203/225084
Appears in Collection
CH-Journal Papers(저널논문)
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