DC Field | Value | Language |
---|---|---|
dc.contributor.author | Park, Sehoon | ko |
dc.contributor.author | Chang, Sukbok | ko |
dc.date.accessioned | 2017-07-18T06:31:01Z | - |
dc.date.available | 2017-07-18T06:31:01Z | - |
dc.date.created | 2017-07-10 | - |
dc.date.created | 2017-07-10 | - |
dc.date.issued | 2017-06 | - |
dc.identifier.citation | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, v.56, no.27, pp.7720 - 7738 | - |
dc.identifier.issn | 1433-7851 | - |
dc.identifier.uri | http://hdl.handle.net/10203/224871 | - |
dc.description.abstract | Dearomatized N-heterocycles are an important class of structural motifs for organic synthesis and chemical biology. The catalytic dearomative reduction of unactivated N-heteroarenes using silicon and/ or boron-containing compounds as a reductant is one of the most straightforward alternatives to hydrogenation. However, thus far, there are few reported examples on the catalytic reduction of N-heteroaromatic compounds with silane or borane reducing agents. This Review presents recent advances in the catalytic reduction of unactivated N-heteroarenes by hydrosilanes, hydroboranes, silaboranes, and diboranes. The focus is on the chemical reactivity and selectivity of transition-metal or metal-free organocatalyst systems. In addition, the working modes of these catalysis will be described primarily on the basis of experimental mechanistic insight. | - |
dc.language | English | - |
dc.publisher | WILEY-V C H VERLAG GMBH | - |
dc.subject | TRANSITION-METAL-COMPLEXES | - |
dc.subject | TRANSFER HYDROGENATION | - |
dc.subject | PARTIAL REDUCTION | - |
dc.subject | REGIOSELECTIVE 1,4-HYDROBORATION | - |
dc.subject | ASYMMETRIC HYDROGENATION | - |
dc.subject | SILYLATIVE REDUCTION | - |
dc.subject | CARBONYL-COMPOUNDS | - |
dc.subject | ORGANIC-SYNTHESIS | - |
dc.subject | INDOLE ALKALOIDS | - |
dc.subject | HANTZSCH ESTERS | - |
dc.title | Catalytic Dearomatization of N-Heteroarenes with Silicon and Boron Compounds | - |
dc.type | Article | - |
dc.identifier.wosid | 000403839000004 | - |
dc.identifier.scopusid | 2-s2.0-85020169770 | - |
dc.type.rims | ART | - |
dc.citation.volume | 56 | - |
dc.citation.issue | 27 | - |
dc.citation.beginningpage | 7720 | - |
dc.citation.endingpage | 7738 | - |
dc.citation.publicationname | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | - |
dc.identifier.doi | 10.1002/anie.201612140 | - |
dc.contributor.localauthor | Chang, Sukbok | - |
dc.contributor.nonIdAuthor | Park, Sehoon | - |
dc.description.isOpenAccess | N | - |
dc.type.journalArticle | Review | - |
dc.subject.keywordAuthor | boration | - |
dc.subject.keywordAuthor | catalytic reduction | - |
dc.subject.keywordAuthor | dearomatization | - |
dc.subject.keywordAuthor | N-heteroarenes | - |
dc.subject.keywordAuthor | silylation | - |
dc.subject.keywordPlus | TRANSITION-METAL-COMPLEXES | - |
dc.subject.keywordPlus | TRANSFER HYDROGENATION | - |
dc.subject.keywordPlus | PARTIAL REDUCTION | - |
dc.subject.keywordPlus | REGIOSELECTIVE 1,4-HYDROBORATION | - |
dc.subject.keywordPlus | ASYMMETRIC HYDROGENATION | - |
dc.subject.keywordPlus | SILYLATIVE REDUCTION | - |
dc.subject.keywordPlus | CARBONYL-COMPOUNDS | - |
dc.subject.keywordPlus | ORGANIC-SYNTHESIS | - |
dc.subject.keywordPlus | INDOLE ALKALOIDS | - |
dc.subject.keywordPlus | HANTZSCH ESTERS | - |
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