Thermodynamic Stability of Structure II Methyl Vinyl Ketone Binary Clathrate Hydrates and Effects of Secondary Guest Molecules on Large Guest Conformation

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Clathrate hydrates have received massive attention because of their potential application as energy storage materials. Host water frameworks of clathrate hydrates provide empty cavities that can capture not only small molecular guests but also radical species induced by gamma-irradiation. In this work, we investigated structure II methyl vinyl ketone (MVK) binary clathrate hydrates with CH4, O-2, and N-2 and the effects of secondary guest species on MVK conformation in the cavity of hydrate and on the thermodynamic stability of unirradiated and gamma-irradiated hydrate phases. The present findings provide meaningful information to understand the nature of guest-host interactions in gamma-irradiated clathrate hydrates and to open up practical applications for hydratebased nanoreactors.
Publisher
AMER CHEMICAL SOC
Issue Date
2017-04
Language
English
Article Type
Article
Citation

ACS OMEGA, v.2, no.4, pp.1601 - 1607

ISSN
2470-1343
DOI
10.1021/acsomega.7b00264
URI
http://hdl.handle.net/10203/224562
Appears in Collection
CBE-Journal Papers(저널논문)
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