New synthesis of 3-deoxypurine nucleosides using samarium(III) iodide complex

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Regio- and stereoselective iodinative cleavage of 2',3'-anhydropurine nucleosides was achieved with samarium diiodide and ethyl bromoacetate to produce the corresponding 3'-iodopurine nucleosides, which were then converted to 3'-deoxypurine nucleosides including the natural product cordycepin. (C) 2003 Elsevier Ltd. All rights reserved.
Publisher
PERGAMON-ELSEVIER SCIENCE LTD
Issue Date
2003-10
Language
English
Article Type
Article
Keywords

EFFICIENT SYNTHESIS; 2-ACYLOXYISOBUTYRYL HALIDES; ADENOSINE; 3' -DEOXYADENOSINE; CORDYCEPIN; ACID; RNA; DNA

Citation

TETRAHEDRON LETTERS, v.44, no.43, pp.7941 - 7943

ISSN
0040-4039
DOI
10.1016/j.tetlet.2003.09.001
URI
http://hdl.handle.net/10203/2245
Appears in Collection
BS-Journal Papers(저널논문)
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