DC Field | Value | Language |
---|---|---|
dc.contributor.author | Cho, Han-Hee | ko |
dc.contributor.author | Kim, Taesu | ko |
dc.contributor.author | Kim, Kimyung | ko |
dc.contributor.author | Lee, Changyeon | ko |
dc.contributor.author | Kim, Felix Sunjoo | ko |
dc.contributor.author | Kim, Bumjoon J. | ko |
dc.date.accessioned | 2017-04-17T07:42:19Z | - |
dc.date.available | 2017-04-17T07:42:19Z | - |
dc.date.created | 2017-04-10 | - |
dc.date.created | 2017-04-10 | - |
dc.date.issued | 2017-02 | - |
dc.identifier.citation | JOURNAL OF MATERIALS CHEMISTRY A, v.5, no.11, pp.5449 - 5459 | - |
dc.identifier.issn | 2050-7488 | - |
dc.identifier.uri | http://hdl.handle.net/10203/223352 | - |
dc.description.abstract | We designed and synthesized a series of n-type conjugated polymers by introducing phenylnaphthalenediimide (PNDI) as a novel n-type building block, and investigated the effect of side-chain engineering of the polymer acceptors on the performance of all-polymer solar cells (all-PSCs). The optical, electrochemical, and structural properties of the polymers with three different side chains of 2-ethylhexyl (PPNDI-EH), 2-butyloctyl (PPNDI-BO), and 2-hexyldecyl (PPNDI-HD) groups were examined. Interestingly, the PNDI-based polymer having the longest side chain showed a higher degree of edge-on oriented intermolecular assembly in thin films, thereby resulting in the highest field-effect electron mobility among the three polymers. Also, we examined the performance of PNDI-based polymers as polymer acceptors in all-PSCs. Unlike the trend in the field-effect transistor, the PPNDI-BO-based all-PSCs exhibited the highest power conversion efficiency (PCE) of 4.25% among the three polymer blends. This was attributed to the well-balanced hole/electron transport and higher exciton dissociation probability in the PPNDI-BO-based all-PSCs, benefitted from the well-intermixed blend morphology between the polymer donor and PPNDI-BO. | - |
dc.language | English | - |
dc.publisher | ROYAL SOC CHEMISTRY | - |
dc.subject | POWER CONVERSION EFFICIENCY | - |
dc.subject | FIELD-EFFECT TRANSISTORS | - |
dc.subject | HIGH-ELECTRON-MOBILITY | - |
dc.subject | LOW-BANDGAP POLYMERS | - |
dc.subject | NAPHTHALENE DIIMIDE | - |
dc.subject | HIGH-PERFORMANCE | - |
dc.subject | CONJUGATED POLYMERS | - |
dc.subject | PHOTOVOLTAIC PROPERTIES | - |
dc.subject | BROAD ABSORPTION | - |
dc.subject | ADDITIVE-FREE | - |
dc.title | Synthesis and side-chain engineering of phenylnaphthalenediimide (PNDI)-based n-type polymers for efficient all-polymer solar cells | - |
dc.type | Article | - |
dc.identifier.wosid | 000397605300024 | - |
dc.identifier.scopusid | 2-s2.0-85015435290 | - |
dc.type.rims | ART | - |
dc.citation.volume | 5 | - |
dc.citation.issue | 11 | - |
dc.citation.beginningpage | 5449 | - |
dc.citation.endingpage | 5459 | - |
dc.citation.publicationname | JOURNAL OF MATERIALS CHEMISTRY A | - |
dc.identifier.doi | 10.1039/c6ta10978k | - |
dc.contributor.localauthor | Kim, Bumjoon J. | - |
dc.contributor.nonIdAuthor | Kim, Kimyung | - |
dc.contributor.nonIdAuthor | Kim, Felix Sunjoo | - |
dc.description.isOpenAccess | N | - |
dc.type.journalArticle | Article | - |
dc.subject.keywordPlus | POWER CONVERSION EFFICIENCY | - |
dc.subject.keywordPlus | FIELD-EFFECT TRANSISTORS | - |
dc.subject.keywordPlus | HIGH-ELECTRON-MOBILITY | - |
dc.subject.keywordPlus | LOW-BANDGAP POLYMERS | - |
dc.subject.keywordPlus | NAPHTHALENE DIIMIDE | - |
dc.subject.keywordPlus | HIGH-PERFORMANCE | - |
dc.subject.keywordPlus | CONJUGATED POLYMERS | - |
dc.subject.keywordPlus | PHOTOVOLTAIC PROPERTIES | - |
dc.subject.keywordPlus | BROAD ABSORPTION | - |
dc.subject.keywordPlus | ADDITIVE-FREE | - |
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