Non-native transition metal monoxide nanostructures: unique physicochemical properties and phase transformations of CoO, MnO and ZnO

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The discovery of unprecedented, non-native phases of transition metal oxides is a fascinating theme in materials chemistry, including the development of new synthetic strategies with excellent size-and phase-selectivity, and elucidation of their unique physicochemical properties. Most of the first-row transition metal monoxides, such as MnO, FeO, CoO and NiO, are known to exist in a cubic phase, but only ZnO adopts a hexagonal structure. This review summarizes recent results on the syntheses and characterization of the non-native phases of h-CoO, h-MnO and c-ZnO transition metal monoxides, compared to their native phases. The investigation of the size-and phase-selective synthetic methods, formation mechanism and unique physicochemical properties of non-native transition metal monoxides would have an enormous impact on materials chemistry and open a promising avenue for magnetic, electronic and spintronic applications.
Publisher
NATURE PUBLISHING GROUP
Issue Date
2017-03
Language
English
Article Type
Review
Keywords

LITHIUM-ION BATTERIES; CRYSTAL-STRUCTURE; HIGH-PRESSURE; WURTZITE COO; HYDROTHERMAL SYNTHESIS; OXIDE NANOPARTICLES; MAGNETIC-PROPERTIES; CHEMICAL APPROACH; ROOM-TEMPERATURE; MANGANESE OXIDES

Citation

NPG ASIA MATERIALS, v.9

ISSN
1884-4049
DOI
10.1038/am.2017.38
URI
http://hdl.handle.net/10203/223231
Appears in Collection
CH-Journal Papers(저널논문)
Files in This Item
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