DC Field | Value | Language |
---|---|---|
dc.contributor.author | Hong, Seung Youn | ko |
dc.contributor.author | Jeong, Jisu | ko |
dc.contributor.author | Chang, Sukbok | ko |
dc.date.accessioned | 2017-04-14T08:14:06Z | - |
dc.date.available | 2017-04-14T08:14:06Z | - |
dc.date.created | 2017-04-04 | - |
dc.date.created | 2017-04-04 | - |
dc.date.issued | 2017-02 | - |
dc.identifier.citation | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, v.56, no.9, pp.2408 - 2412 | - |
dc.identifier.issn | 1433-7851 | - |
dc.identifier.uri | http://hdl.handle.net/10203/223026 | - |
dc.description.abstract | A change in reaction pathway was achieved for the first time by tuning the cyclopentadienyl (Cp) ligand used for the rhodium-catalyzed cyclization of benzamides with conjugated enynones. Depending on the Cp ligand, the reaction pathway switched between [4+2] and [4+1] annulation. Electronic effects turned out to be crucial for the product distribution. The dichotomy was attributed to the alteration of the Lewis acidity of the resultant Cp-bound rhodium species. | - |
dc.language | English | - |
dc.publisher | WILEY-V C H VERLAG GMBH | - |
dc.subject | C-H ACTIVATION | - |
dc.subject | N BOND FORMATION | - |
dc.subject | CYCLOPENTADIENYL LIGANDS | - |
dc.subject | AMBIENT CONDITIONS | - |
dc.subject | FACILE SYNTHESIS | - |
dc.subject | DIAZO-COMPOUNDS | - |
dc.subject | DIRECTING GROUP | - |
dc.subject | OXIME ESTERS | - |
dc.subject | ALKENES | - |
dc.subject | FUNCTIONALIZATION | - |
dc.title | [4+2] or [4+1] Annulation: Changing the Reaction Pathway of a Rhodium-Catalyzed Process by Tuning the CpLigand | - |
dc.type | Article | - |
dc.identifier.wosid | 000395566600029 | - |
dc.identifier.scopusid | 2-s2.0-85010425283 | - |
dc.type.rims | ART | - |
dc.citation.volume | 56 | - |
dc.citation.issue | 9 | - |
dc.citation.beginningpage | 2408 | - |
dc.citation.endingpage | 2412 | - |
dc.citation.publicationname | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | - |
dc.identifier.doi | 10.1002/anie.201612559 | - |
dc.contributor.localauthor | Chang, Sukbok | - |
dc.description.isOpenAccess | N | - |
dc.type.journalArticle | Article | - |
dc.subject.keywordAuthor | annulations | - |
dc.subject.keywordAuthor | cyclopentadienyl ligands | - |
dc.subject.keywordAuthor | reaction mechanisms | - |
dc.subject.keywordAuthor | rhodium catalysis | - |
dc.subject.keywordPlus | C-H ACTIVATION | - |
dc.subject.keywordPlus | N BOND FORMATION | - |
dc.subject.keywordPlus | CYCLOPENTADIENYL LIGANDS | - |
dc.subject.keywordPlus | AMBIENT CONDITIONS | - |
dc.subject.keywordPlus | FACILE SYNTHESIS | - |
dc.subject.keywordPlus | DIAZO-COMPOUNDS | - |
dc.subject.keywordPlus | DIRECTING GROUP | - |
dc.subject.keywordPlus | OXIME ESTERS | - |
dc.subject.keywordPlus | ALKENES | - |
dc.subject.keywordPlus | FUNCTIONALIZATION | - |
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