DSpace at KOASAS
College of Natural Sciences(자연과학대학)Dept. of Chemistry(화학과)CH-Journal Papers(저널논문)

[4+2] or [4+1] Annulation: Changing the Reaction Pathway of a Rhodium-Catalyzed Process by Tuning the CpLigand

Cited 131 time in webofscience Cited 0 time in scopus
  • Hit : 494
  • Download : 0
Export
DC FieldValueLanguage
dc.contributor.authorHong, Seung Younko
dc.contributor.authorJeong, Jisuko
dc.contributor.authorChang, Sukbokko
dc.date.accessioned2017-04-14T08:14:06Z-
dc.date.available2017-04-14T08:14:06Z-
dc.date.created2017-04-04-
dc.date.created2017-04-04-
dc.date.issued2017-02-
dc.identifier.citationANGEWANDTE CHEMIE-INTERNATIONAL EDITION, v.56, no.9, pp.2408 - 2412-
dc.identifier.issn1433-7851-
dc.identifier.urihttp://hdl.handle.net/10203/223026-
dc.description.abstractA change in reaction pathway was achieved for the first time by tuning the cyclopentadienyl (Cp) ligand used for the rhodium-catalyzed cyclization of benzamides with conjugated enynones. Depending on the Cp ligand, the reaction pathway switched between [4+2] and [4+1] annulation. Electronic effects turned out to be crucial for the product distribution. The dichotomy was attributed to the alteration of the Lewis acidity of the resultant Cp-bound rhodium species.-
dc.languageEnglish-
dc.publisherWILEY-V C H VERLAG GMBH-
dc.subjectC-H ACTIVATION-
dc.subjectN BOND FORMATION-
dc.subjectCYCLOPENTADIENYL LIGANDS-
dc.subjectAMBIENT CONDITIONS-
dc.subjectFACILE SYNTHESIS-
dc.subjectDIAZO-COMPOUNDS-
dc.subjectDIRECTING GROUP-
dc.subjectOXIME ESTERS-
dc.subjectALKENES-
dc.subjectFUNCTIONALIZATION-
dc.title[4+2] or [4+1] Annulation: Changing the Reaction Pathway of a Rhodium-Catalyzed Process by Tuning the CpLigand-
dc.typeArticle-
dc.identifier.wosid000395566600029-
dc.identifier.scopusid2-s2.0-85010425283-
dc.type.rimsART-
dc.citation.volume56-
dc.citation.issue9-
dc.citation.beginningpage2408-
dc.citation.endingpage2412-
dc.citation.publicationnameANGEWANDTE CHEMIE-INTERNATIONAL EDITION-
dc.identifier.doi10.1002/anie.201612559-
dc.contributor.localauthorChang, Sukbok-
dc.description.isOpenAccessN-
dc.type.journalArticleArticle-
dc.subject.keywordAuthorannulations-
dc.subject.keywordAuthorcyclopentadienyl ligands-
dc.subject.keywordAuthorreaction mechanisms-
dc.subject.keywordAuthorrhodium catalysis-
dc.subject.keywordPlusC-H ACTIVATION-
dc.subject.keywordPlusN BOND FORMATION-
dc.subject.keywordPlusCYCLOPENTADIENYL LIGANDS-
dc.subject.keywordPlusAMBIENT CONDITIONS-
dc.subject.keywordPlusFACILE SYNTHESIS-
dc.subject.keywordPlusDIAZO-COMPOUNDS-
dc.subject.keywordPlusDIRECTING GROUP-
dc.subject.keywordPlusOXIME ESTERS-
dc.subject.keywordPlusALKENES-
dc.subject.keywordPlusFUNCTIONALIZATION-
Appears in Collection
CH-Journal Papers(저널논문)
Files in This Item
There are no files associated with this item.
This item is cited by other documents in WoS
⊙ Detail Information in WoSⓡ Click to see webofscience_button
⊙ Cited 131 items in WoS Click to see citing articles in records_button

Display Simple Item Record

qr_code

  • mendeley

    citeulike

Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.


rss_1.0 rss_2.0 atom_1.0