DC Field | Value | Language |
---|---|---|
dc.contributor.author | Lee, Jihong | ko |
dc.contributor.author | Kim, Kyung Hwan | ko |
dc.contributor.author | Lee, Ok Suk | ko |
dc.contributor.author | Choi, Tae-Lim | ko |
dc.contributor.author | Lee, Hee-Seung | ko |
dc.contributor.author | Ihee, Hyotcherl | ko |
dc.contributor.author | Sohn, Jeong-Hun | ko |
dc.date.accessioned | 2016-11-09T02:37:53Z | - |
dc.date.available | 2016-11-09T02:37:53Z | - |
dc.date.created | 2016-10-05 | - |
dc.date.created | 2016-10-05 | - |
dc.date.issued | 2016-09 | - |
dc.identifier.citation | JOURNAL OF ORGANIC CHEMISTRY, v.81, no.17, pp.7591 - 7596 | - |
dc.identifier.issn | 0022-3263 | - |
dc.identifier.uri | http://hdl.handle.net/10203/213507 | - |
dc.description.abstract | As a guide for selective reactions toward either Z- or E-alkene in a metathesis reaction, the relative preference of metathesis Ru catalysts for each stereoisomer was determined by a method using time-dependent fluorescence quenching. We found that Ru-1 prefers the Z-isomer over the E-isomer, whereas Ru-2 prefers the E-isomer over the Z-isomer. The Z/E-alkene preference of the catalysts precisely predicted the Z/E isomeric selectivity in the metathesis reactions of diene substrates possessing combinations of Z/E-alkenes. For the diene substrates, the rate order of the reactions using Ru-1 was Z,Z-1,6-diene > Z,E-1,6-diene > E,E-1,6-diene, while the completely opposite order of E,E-1,6-diene > Z,E-1,6-diene > Z,Z-1,6-diene was exhibited in the case of Ru-2 | - |
dc.language | English | - |
dc.publisher | AMER CHEMICAL SOC | - |
dc.subject | RESONANCE ENERGY-TRANSFER | - |
dc.subject | RING-CLOSING METATHESIS | - |
dc.subject | STEREOSELECTIVE OLEFIN METATHESIS | - |
dc.subject | HETEROCYCLIC CARBENE LIGANDS | - |
dc.subject | CROSS-METATHESIS | - |
dc.subject | OPENING/CROSS-METATHESIS | - |
dc.subject | ENYNE METATHESIS | - |
dc.subject | TERMINAL OLEFINS | - |
dc.subject | RU CARBENES | - |
dc.subject | COMPLEXES | - |
dc.title | Preference of Ruthenium-Based Metathesis Catalysts toward Z- and E-Alkenes as a Guide for Selective Reactions to Alkene Stereoisomers | - |
dc.type | Article | - |
dc.identifier.wosid | 000382713800028 | - |
dc.identifier.scopusid | 2-s2.0-84984905381 | - |
dc.type.rims | ART | - |
dc.citation.volume | 81 | - |
dc.citation.issue | 17 | - |
dc.citation.beginningpage | 7591 | - |
dc.citation.endingpage | 7596 | - |
dc.citation.publicationname | JOURNAL OF ORGANIC CHEMISTRY | - |
dc.identifier.doi | 10.1021/acs.joc.6b01276 | - |
dc.contributor.localauthor | Lee, Hee-Seung | - |
dc.contributor.localauthor | Ihee, Hyotcherl | - |
dc.contributor.nonIdAuthor | Lee, Jihong | - |
dc.contributor.nonIdAuthor | Kim, Kyung Hwan | - |
dc.contributor.nonIdAuthor | Lee, Ok Suk | - |
dc.contributor.nonIdAuthor | Choi, Tae-Lim | - |
dc.contributor.nonIdAuthor | Sohn, Jeong-Hun | - |
dc.type.journalArticle | Article | - |
dc.subject.keywordPlus | RESONANCE ENERGY-TRANSFER | - |
dc.subject.keywordPlus | RING-CLOSING METATHESIS | - |
dc.subject.keywordPlus | STEREOSELECTIVE OLEFIN METATHESIS | - |
dc.subject.keywordPlus | HETEROCYCLIC CARBENE LIGANDS | - |
dc.subject.keywordPlus | CROSS-METATHESIS | - |
dc.subject.keywordPlus | OPENING/CROSS-METATHESIS | - |
dc.subject.keywordPlus | ENYNE METATHESIS | - |
dc.subject.keywordPlus | TERMINAL OLEFINS | - |
dc.subject.keywordPlus | RU CARBENES | - |
dc.subject.keywordPlus | COMPLEXES | - |
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