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College of Natural Sciences(자연과학대학)Dept. of Chemistry(화학과)CH-Journal Papers(저널논문)

The unusual hydridicity of a cobalt bound Si-H moiety

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dc.contributor.authorKim, Jinko
dc.contributor.authorKim, Yujeongko
dc.contributor.authorSinha, Indranilko
dc.contributor.authorPark, Koeunko
dc.contributor.authorKim, Sun Heeko
dc.contributor.authorLee, Yunhoko
dc.date.accessioned2016-09-07T01:09:25Z-
dc.date.available2016-09-07T01:09:25Z-
dc.date.created2016-07-01-
dc.date.created2016-07-01-
dc.date.issued2016-
dc.identifier.citationCHEMICAL COMMUNICATIONS, v.52, no.60, pp.9367 - 9370-
dc.identifier.issn1359-7345-
dc.identifier.urihttp://hdl.handle.net/10203/212510-
dc.description.abstractA paramagnetic cobalt-SiH intermediate possessing the Co-(eta(1)-H-Si) moiety was studied using various spectroscopic techniques. Frozen solution ENDOR experiments show a Co-H distance of similar to 1.53 angstrom and a Si-Co-H angle of similar to 15 degrees, whereas XRD data suggest a TBP geometry about a Co(II) centre. Its stepwise deprotonation with base followed by dehalogenation was identified experimentally and theoretically.-
dc.languageEnglish-
dc.publisherROYAL SOC CHEMISTRY-
dc.subjectSIGMA-BOND METATHESIS-
dc.subjectTRANSITION-METAL-COMPLEXES-
dc.subjectEFFECTIVE CORE POTENTIALS-
dc.subjectMOLECULAR CALCULATIONS-
dc.subjectSPECTROSCOPIC PROPERTIES-
dc.subjectSTRUCTURAL-ANALYSIS-
dc.subjectOXIDATIVE ADDITION-
dc.subjectSOLUTION ACIDITY-
dc.subjectSILYL COMPLEXES-
dc.subjectLIGAND-
dc.titleThe unusual hydridicity of a cobalt bound Si-H moiety-
dc.typeArticle-
dc.identifier.wosid000379882200009-
dc.identifier.scopusid2-s2.0-84979226400-
dc.type.rimsART-
dc.citation.volume52-
dc.citation.issue60-
dc.citation.beginningpage9367-
dc.citation.endingpage9370-
dc.citation.publicationnameCHEMICAL COMMUNICATIONS-
dc.identifier.doi10.1039/c6cc03983a-
dc.contributor.localauthorLee, Yunho-
dc.contributor.nonIdAuthorKim, Yujeong-
dc.contributor.nonIdAuthorSinha, Indranil-
dc.contributor.nonIdAuthorKim, Sun Hee-
dc.type.journalArticleArticle-
dc.subject.keywordPlusSIGMA-BOND METATHESIS-
dc.subject.keywordPlusTRANSITION-METAL-COMPLEXES-
dc.subject.keywordPlusEFFECTIVE CORE POTENTIALS-
dc.subject.keywordPlusMOLECULAR CALCULATIONS-
dc.subject.keywordPlusSPECTROSCOPIC PROPERTIES-
dc.subject.keywordPlusSTRUCTURAL-ANALYSIS-
dc.subject.keywordPlusOXIDATIVE ADDITION-
dc.subject.keywordPlusSOLUTION ACIDITY-
dc.subject.keywordPlusSILYL COMPLEXES-
dc.subject.keywordPlusLIGAND-
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