Electrochemical studies of C-60-triosmium complexes: First evidence for a C-60-mediated electron transfer to the metal center

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dc.contributor.authorPark, Joon Taikko
dc.contributor.authorCho, JJko
dc.contributor.authorSong, Hyunjoonko
dc.contributor.authorJun, SCko
dc.contributor.authorSon, Yko
dc.contributor.authorKwak, Juhyounko
dc.date.accessioned2010-12-24T05:59:58Z-
dc.date.available2010-12-24T05:59:58Z-
dc.date.created2012-02-06-
dc.date.created2012-02-06-
dc.date.issued1997-06-
dc.identifier.citationINORGANIC CHEMISTRY, v.36, no.13, pp.2698 - 2698-
dc.identifier.issn0020-1669-
dc.identifier.urihttp://hdl.handle.net/10203/21229-
dc.description.abstractThe C-60-triosmium carbonyl complexes Os-3(CO)(11-n)(PPh3)(n)(eta(2)-C-60) [n = 0 (1), n = 1 (2), n = 2 (3)] have been studied by both cyclic voltammetric and IR spectroelectrochemical methods in a dichloromethane-toluene (4:1) solution. Both results suggest that a C-60-mediated electron transfer to the triosmium metal center takes place in these complexes. This is further confirmed by the synthesis and characterization of [NiCp2'](+)1(-) (Cp' = eta(5)-C5Me5). The three sequential one-electron reduction potentials of 1-3 are in the order of 1 > 2 > 3, respectively, due to the donor effect of the PPh3 ligand. Reduction is accompanied by loss of the C-60 moiety.-
dc.description.sponsorshipWe are grateful to both the Korea Science and Engineering Foundation and the Korea Advanced Instituteof Science and Technology for financial support of this research.en
dc.languageEnglish-
dc.language.isoen_USen
dc.publisherAMER CHEMICAL SOC-
dc.subjectBUCKMINSTERFULLERENE C-60-
dc.subjectDERIVATIVES-
dc.titleElectrochemical studies of C-60-triosmium complexes: First evidence for a C-60-mediated electron transfer to the metal center-
dc.typeArticle-
dc.identifier.wosidA1997XF30900001-
dc.identifier.scopusid2-s2.0-0000863980-
dc.type.rimsART-
dc.citation.volume36-
dc.citation.issue13-
dc.citation.beginningpage2698-
dc.citation.endingpage2698-
dc.citation.publicationnameINORGANIC CHEMISTRY-
dc.embargo.liftdate9999-12-31-
dc.embargo.terms9999-12-31-
dc.contributor.localauthorPark, Joon Taik-
dc.contributor.localauthorSong, Hyunjoon-
dc.contributor.localauthorKwak, Juhyoun-
dc.contributor.nonIdAuthorCho, JJ-
dc.contributor.nonIdAuthorJun, SC-
dc.contributor.nonIdAuthorSon, Y-
dc.type.journalArticleArticle-
dc.subject.keywordPlusBUCKMINSTERFULLERENE C-60-
dc.subject.keywordPlusDERIVATIVES-
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