DC Field | Value | Language |
---|---|---|
dc.contributor.author | Park, Joon Taik | ko |
dc.contributor.author | Cho, JJ | ko |
dc.contributor.author | Song, Hyunjoon | ko |
dc.contributor.author | Jun, SC | ko |
dc.contributor.author | Son, Y | ko |
dc.contributor.author | Kwak, Juhyoun | ko |
dc.date.accessioned | 2010-12-24T05:59:58Z | - |
dc.date.available | 2010-12-24T05:59:58Z | - |
dc.date.created | 2012-02-06 | - |
dc.date.created | 2012-02-06 | - |
dc.date.issued | 1997-06 | - |
dc.identifier.citation | INORGANIC CHEMISTRY, v.36, no.13, pp.2698 - 2698 | - |
dc.identifier.issn | 0020-1669 | - |
dc.identifier.uri | http://hdl.handle.net/10203/21229 | - |
dc.description.abstract | The C-60-triosmium carbonyl complexes Os-3(CO)(11-n)(PPh3)(n)(eta(2)-C-60) [n = 0 (1), n = 1 (2), n = 2 (3)] have been studied by both cyclic voltammetric and IR spectroelectrochemical methods in a dichloromethane-toluene (4:1) solution. Both results suggest that a C-60-mediated electron transfer to the triosmium metal center takes place in these complexes. This is further confirmed by the synthesis and characterization of [NiCp2'](+)1(-) (Cp' = eta(5)-C5Me5). The three sequential one-electron reduction potentials of 1-3 are in the order of 1 > 2 > 3, respectively, due to the donor effect of the PPh3 ligand. Reduction is accompanied by loss of the C-60 moiety. | - |
dc.description.sponsorship | We are grateful to both the Korea Science and Engineering Foundation and the Korea Advanced Instituteof Science and Technology for financial support of this research. | en |
dc.language | English | - |
dc.language.iso | en_US | en |
dc.publisher | AMER CHEMICAL SOC | - |
dc.subject | BUCKMINSTERFULLERENE C-60 | - |
dc.subject | DERIVATIVES | - |
dc.title | Electrochemical studies of C-60-triosmium complexes: First evidence for a C-60-mediated electron transfer to the metal center | - |
dc.type | Article | - |
dc.identifier.wosid | A1997XF30900001 | - |
dc.identifier.scopusid | 2-s2.0-0000863980 | - |
dc.type.rims | ART | - |
dc.citation.volume | 36 | - |
dc.citation.issue | 13 | - |
dc.citation.beginningpage | 2698 | - |
dc.citation.endingpage | 2698 | - |
dc.citation.publicationname | INORGANIC CHEMISTRY | - |
dc.embargo.liftdate | 9999-12-31 | - |
dc.embargo.terms | 9999-12-31 | - |
dc.contributor.localauthor | Park, Joon Taik | - |
dc.contributor.localauthor | Song, Hyunjoon | - |
dc.contributor.localauthor | Kwak, Juhyoun | - |
dc.contributor.nonIdAuthor | Cho, JJ | - |
dc.contributor.nonIdAuthor | Jun, SC | - |
dc.contributor.nonIdAuthor | Son, Y | - |
dc.type.journalArticle | Article | - |
dc.subject.keywordPlus | BUCKMINSTERFULLERENE C-60 | - |
dc.subject.keywordPlus | DERIVATIVES | - |
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