DC Field | Value | Language |
---|---|---|
dc.contributor.author | Hwang, JW | ko |
dc.contributor.author | Kim, JH | ko |
dc.contributor.author | Lee, H | ko |
dc.contributor.author | Lee, H | ko |
dc.contributor.author | Kim, Sehun | ko |
dc.contributor.author | Kwak, Juhyoun | ko |
dc.contributor.author | Do, Youngkyu | ko |
dc.date.accessioned | 2010-12-22T06:47:19Z | - |
dc.date.available | 2010-12-22T06:47:19Z | - |
dc.date.created | 2012-02-06 | - |
dc.date.created | 2012-02-06 | - |
dc.date.issued | 2001-09 | - |
dc.identifier.citation | JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, v.123, no.37, pp.9054 - 9063 | - |
dc.identifier.issn | 0002-7863 | - |
dc.identifier.uri | http://hdl.handle.net/10203/21181 | - |
dc.description.abstract | The synthesis and structural analysis of two novel families of three-component reversible redox cycles [(C2B9H11)M(mu -SPh)(2)](2)(PPNn)-P-n (M = Mo, n = 2-, 2; 1-, 3; 0, 4; and M = W, n = 2-, 6; 1-, 7; 0, 8), where the cleavage and re-formation of the carborane cage C-C bond is observed during the redox reaction, are reported. Electronic saturation of the metal center (18e center) and the lack of bulky substituents on the carborane cage suggest that the deformed carborane cages in 2.PPN2, 6.PPN2, and 7.PPN invoke a new kind of deformed cage ("semicloso" framework). The XPS results show that the unprecedented competition for electron density between the metal center and the carborane cage is involved in the cleavage and formation of the carborane C-C bond. | - |
dc.description.sponsorship | This research was supported by the Korea Science and Engineering Foundation and the Brain Korea 21 Project. | en |
dc.language | English | - |
dc.language.iso | en_US | en |
dc.publisher | AMER CHEMICAL SOC | - |
dc.subject | HYPER-CLOSO METALLABORANES | - |
dc.subject | MOLECULAR-STRUCTURE | - |
dc.subject | CRYSTAL-STRUCTURE | - |
dc.subject | CLUSTER COMPOUNDS | - |
dc.subject | METAL-COMPLEXES | - |
dc.subject | BLOCK ELEMENTS | - |
dc.subject | OXIDATION | - |
dc.subject | CHEMISTRY | - |
dc.subject | LIGANDS | - |
dc.subject | TRICARBONYLMOLYBDACARBORANE | - |
dc.title | Novel families of three-component reversible redox cycles involving cage deformation via intramolecular redox reaction: Tetrathiolate-bridged dinuclear molybda- and tungstacarboranes | - |
dc.type | Article | - |
dc.identifier.wosid | 000170956300020 | - |
dc.identifier.scopusid | 2-s2.0-0035913757 | - |
dc.type.rims | ART | - |
dc.citation.volume | 123 | - |
dc.citation.issue | 37 | - |
dc.citation.beginningpage | 9054 | - |
dc.citation.endingpage | 9063 | - |
dc.citation.publicationname | JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | - |
dc.embargo.liftdate | 9999-12-31 | - |
dc.embargo.terms | 9999-12-31 | - |
dc.contributor.localauthor | Kim, Sehun | - |
dc.contributor.localauthor | Kwak, Juhyoun | - |
dc.contributor.localauthor | Do, Youngkyu | - |
dc.contributor.nonIdAuthor | Hwang, JW | - |
dc.contributor.nonIdAuthor | Kim, JH | - |
dc.contributor.nonIdAuthor | Lee, H | - |
dc.contributor.nonIdAuthor | Lee, H | - |
dc.type.journalArticle | Article | - |
dc.subject.keywordPlus | HYPER-CLOSO METALLABORANES | - |
dc.subject.keywordPlus | MOLECULAR-STRUCTURE | - |
dc.subject.keywordPlus | CRYSTAL-STRUCTURE | - |
dc.subject.keywordPlus | CLUSTER COMPOUNDS | - |
dc.subject.keywordPlus | METAL-COMPLEXES | - |
dc.subject.keywordPlus | BLOCK ELEMENTS | - |
dc.subject.keywordPlus | OXIDATION | - |
dc.subject.keywordPlus | CHEMISTRY | - |
dc.subject.keywordPlus | LIGANDS | - |
dc.subject.keywordPlus | TRICARBONYLMOLYBDACARBORANE | - |
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.