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College of Natural Sciences(자연과학대학)Dept. of Chemistry(화학과)CH-Journal Papers(저널논문)

Syndiotactic polystyrene with very high molecular weight produced by sterically and electronically modified catalyst

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dc.contributor.authorKim, Yko
dc.contributor.authorDo, Youngkyuko
dc.date.accessioned2007-11-22T01:40:14Z-
dc.date.available2007-11-22T01:40:14Z-
dc.date.created2012-02-06-
dc.date.created2012-02-06-
dc.date.issued2002-08-
dc.identifier.citationJOURNAL OF ORGANOMETALLIC CHEMISTRY, v.655, no.1-2, pp.186 - 191-
dc.identifier.issn0022-328X-
dc.identifier.urihttp://hdl.handle.net/10203/2101-
dc.description.abstractA new type of the half-metallocene catalysts for the syndiospecific polymerization of styrene was prepared by the reaction of various kinds of trialkanolamine with Cp*TiCl3 in the presence of triethylamine. All seven compounds have a highly thermal stability and they show fairly good activities in the presence of cocatalyst MMAO in styrene polymerization. Especially, highly bulky and electronically deficient 7/MMAO system affords syndiotactic polystyrene with very high molecular weight. (C) 2002 Published by Elsevier Science B.V.-
dc.description.sponsorshipKorea Science and Engineering Foundation and the Brain Korea 21 Projecten
dc.languageEnglish-
dc.language.isoen_USen
dc.publisherELSEVIER SCIENCE SA-
dc.subjectSYNDIOSPECIFIC STYRENE POLYMERIZATION-
dc.subjectSTEREOSPECIFIC POLYMERIZATION-
dc.subjectSTEREOCHEMICAL CONTROL-
dc.subjectMETALLOCENE CATALYSTS-
dc.subjectTITANIUM COMPLEXES-
dc.subjectPOLYETHYLENE-
dc.titleSyndiotactic polystyrene with very high molecular weight produced by sterically and electronically modified catalyst-
dc.typeArticle-
dc.identifier.wosid000176957500024-
dc.identifier.scopusid2-s2.0-0036681365-
dc.type.rimsART-
dc.citation.volume655-
dc.citation.issue1-2-
dc.citation.beginningpage186-
dc.citation.endingpage191-
dc.citation.publicationnameJOURNAL OF ORGANOMETALLIC CHEMISTRY-
dc.embargo.liftdate9999-12-31-
dc.embargo.terms9999-12-31-
dc.contributor.localauthorDo, Youngkyu-
dc.contributor.nonIdAuthorKim, Y-
dc.type.journalArticleArticle-
dc.subject.keywordAuthorhalf-metallocene-
dc.subject.keywordAuthorsyndiotactic polystyrene-
dc.subject.keywordAuthortriethanolamine-
dc.subject.keywordAuthorhigh molecular weight-
dc.subject.keywordAuthorN,N,N-tris((R)-2-phenylethanol)amine-
dc.subject.keywordAuthorpentamethylcyclopentadienyl-
dc.subject.keywordAuthorchiral ligand-
dc.subject.keywordAuthortitanium-
dc.subject.keywordPlusSYNDIOSPECIFIC STYRENE POLYMERIZATION-
dc.subject.keywordPlusSTEREOSPECIFIC POLYMERIZATION-
dc.subject.keywordPlusSTEREOCHEMICAL CONTROL-
dc.subject.keywordPlusMETALLOCENE CATALYSTS-
dc.subject.keywordPlusTITANIUM COMPLEXES-
dc.subject.keywordPlusPOLYETHYLENE-
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