DC Field | Value | Language |
---|---|---|
dc.contributor.author | Yoo, Changho | ko |
dc.contributor.author | Lee, Yunho | ko |
dc.date.accessioned | 2016-07-07T05:38:33Z | - |
dc.date.available | 2016-07-07T05:38:33Z | - |
dc.date.created | 2016-06-03 | - |
dc.date.created | 2016-06-03 | - |
dc.date.issued | 2016-03 | - |
dc.identifier.citation | INORGANIC CHEMISTRY FRONTIERS, v.3, no.6, pp.849 - 855 | - |
dc.identifier.issn | 2052-1553 | - |
dc.identifier.uri | http://hdl.handle.net/10203/209850 | - |
dc.description.abstract | The reaction of a zerovalent nickel complex {Na}{(PNP)Ni(CO)} (1) with CO2(g) results in the formation of a tetrameric cluster complex {((PNP)-P-COONa)Ni(CO)(2)}(4) (2) as the major product along with {(PNP)Ni}(2)-mu CO3-kappa O-2,O (3), {(PNP)Ni}(2)-mu-CO2-kappa C-2,O (4) and (PNP)Ni(CO) (5). A labelling experiment with (CO2)-C-13(g) reveals that not only the carbamate moeity but also the CO ligand in 2 originate from CO2(g). The formation of both a carbonyl species 2 and a carbonate species 3 indicates that nickel-mediated reductive disproportionation of CO2 occurs. Alternatively, a direct CO2 oxidative reaction of 1 occurs to produce {(PNP)Ni}(2)-mu-CO2-kappa C-2,O (4) in a minor pathway. The synthesis and characterization of 2 and other products are described herein. | - |
dc.language | English | - |
dc.publisher | CHINESE CHEMICAL SOC | - |
dc.subject | CARBON-DIOXIDE | - |
dc.subject | REDUCTIVE DISPROPORTIONATION | - |
dc.subject | COMPLEXES | - |
dc.subject | CLEAVAGE | - |
dc.subject | CS2 | - |
dc.subject | TRANSFORMATION | - |
dc.subject | LIGANDS | - |
dc.subject | BLOCK | - |
dc.title | Formation of a tetranickel octacarbonyl cluster from the CO2 reaction of a zero-valent nickel monocarbonyl species | - |
dc.type | Article | - |
dc.identifier.wosid | 000378516300011 | - |
dc.identifier.scopusid | 2-s2.0-84974658539 | - |
dc.type.rims | ART | - |
dc.citation.volume | 3 | - |
dc.citation.issue | 6 | - |
dc.citation.beginningpage | 849 | - |
dc.citation.endingpage | 855 | - |
dc.citation.publicationname | INORGANIC CHEMISTRY FRONTIERS | - |
dc.identifier.doi | 10.1039/C6QI00011H | - |
dc.contributor.localauthor | Lee, Yunho | - |
dc.type.journalArticle | Article | - |
dc.subject.keywordPlus | CARBON-DIOXIDE | - |
dc.subject.keywordPlus | REDUCTIVE DISPROPORTIONATION | - |
dc.subject.keywordPlus | COMPLEXES | - |
dc.subject.keywordPlus | CLEAVAGE | - |
dc.subject.keywordPlus | CS2 | - |
dc.subject.keywordPlus | TRANSFORMATION | - |
dc.subject.keywordPlus | LIGANDS | - |
dc.subject.keywordPlus | BLOCK | - |
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