DC Field | Value | Language |
---|---|---|
dc.contributor.author | Kim, Hyunwoo | ko |
dc.contributor.author | Chang, Sukbok | ko |
dc.date.accessioned | 2016-07-04T03:10:59Z | - |
dc.date.available | 2016-07-04T03:10:59Z | - |
dc.date.created | 2016-05-10 | - |
dc.date.created | 2016-05-10 | - |
dc.date.issued | 2016-04 | - |
dc.identifier.citation | ACS CATALYSIS, v.6, no.4, pp.2341 - 2351 | - |
dc.identifier.issn | 2155-5435 | - |
dc.identifier.uri | http://hdl.handle.net/10203/209015 | - |
dc.description.abstract | Cross-dehydrogenative couplings (CDCs) have become one of the most straightforward protocols in the CH bond functionalizations, showing step- and atom-efficiency without need of prefunctionalization of substrates and reactants. However, catalytic CH amination procedures based on the CDC strategy by employing amine reactants are considered to be challenging mainly due to the highly nucleophilic character of parent amines to inhibit the catalytic turnovers and the difficulty in optimizing proper oxidative conditions. In spite of these concerns, recent efforts have led to notable advances in the CH amination procedures, particularly in the intermolecular reaction system. In this Perspective, we address the recent achievements in the transition-metal-mediated CDC amination reactions with two types of hydrocarbon substrates: (i) direct amination of acidic CH bonds with parent amines and (ii) chelation-assisted CDC amination/amidation of nonacidic CH bonds. Mechanistic aspects are also briefly delineated in representative amination reactions to provide insights for the future development of highly practical and more environmentally benign processes | - |
dc.language | English | - |
dc.publisher | AMER CHEMICAL SOC | - |
dc.subject | CATALYZED DIRECT AMINATION | - |
dc.subject | CARBON-NITROGEN BONDS | - |
dc.subject | ARYL HALIDES | - |
dc.subject | FUNCTIONALIZATION REACTIONS | - |
dc.subject | EFFICIENT SYNTHESIS | - |
dc.subject | COUPLING REACTIONS | - |
dc.subject | DIRECT AMIDATION | - |
dc.subject | COPPER | - |
dc.subject | AZIDES | - |
dc.subject | COMPLEXES | - |
dc.title | Transition-Metal-Mediated Direct C-H Amination of Hydrocarbons with Amine Reactants: The Most Desirable but Challenging C-N Bond-Formation Approach | - |
dc.type | Article | - |
dc.identifier.wosid | 000373524400023 | - |
dc.identifier.scopusid | 2-s2.0-84963490897 | - |
dc.type.rims | ART | - |
dc.citation.volume | 6 | - |
dc.citation.issue | 4 | - |
dc.citation.beginningpage | 2341 | - |
dc.citation.endingpage | 2351 | - |
dc.citation.publicationname | ACS CATALYSIS | - |
dc.identifier.doi | 10.1021/acscatal.6b00293 | - |
dc.contributor.localauthor | Chang, Sukbok | - |
dc.contributor.nonIdAuthor | Kim, Hyunwoo | - |
dc.type.journalArticle | Article | - |
dc.subject.keywordAuthor | C-H amination | - |
dc.subject.keywordAuthor | cross-dehydrogenative couplings | - |
dc.subject.keywordAuthor | amine reactants | - |
dc.subject.keywordAuthor | transition-metal catalysis | - |
dc.subject.keywordAuthor | oxidative coupling | - |
dc.subject.keywordPlus | CATALYZED DIRECT AMINATION | - |
dc.subject.keywordPlus | CARBON-NITROGEN BONDS | - |
dc.subject.keywordPlus | ARYL HALIDES | - |
dc.subject.keywordPlus | FUNCTIONALIZATION REACTIONS | - |
dc.subject.keywordPlus | EFFICIENT SYNTHESIS | - |
dc.subject.keywordPlus | COUPLING REACTIONS | - |
dc.subject.keywordPlus | DIRECT AMIDATION | - |
dc.subject.keywordPlus | COPPER | - |
dc.subject.keywordPlus | AZIDES | - |
dc.subject.keywordPlus | COMPLEXES | - |
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