DC Field | Value | Language |
---|---|---|
dc.contributor.author | Hong, Seung Youn | ko |
dc.contributor.author | Kwak, Jaesung | ko |
dc.contributor.author | Chang, Sukbok | ko |
dc.date.accessioned | 2016-05-16T08:46:55Z | - |
dc.date.available | 2016-05-16T08:46:55Z | - |
dc.date.created | 2016-03-14 | - |
dc.date.created | 2016-03-14 | - |
dc.date.issued | 2016 | - |
dc.identifier.citation | CHEMICAL COMMUNICATIONS, v.52, no.15, pp.3159 - 3162 | - |
dc.identifier.issn | 1359-7345 | - |
dc.identifier.uri | http://hdl.handle.net/10203/207443 | - |
dc.description.abstract | Reported herein is the first example of the Rh(NHC)-catalyzed selective bis C-H alkylation of NNN tridentate chelating compounds in reaction with alkenes. The observed excellent site-selectivity can readily be explained by the postulated rollover pathway in the C-H bond activation step. The reaction is highly facile affording bis-alkylated tridentate products in high yields over a broad range of versatile heteroarene substrates and alkene reactants including ethylene gas, thus enabling its applications to be feasible in coordination and synthetic chemistry. | - |
dc.language | English | - |
dc.publisher | ROYAL SOC CHEMISTRY | - |
dc.subject | TERPYRIDINE-METAL-COMPLEXES | - |
dc.subject | BOND FUNCTIONALIZATION | - |
dc.subject | HETEROAROMATIC-COMPOUNDS | - |
dc.subject | DIRECT ARYLATION | - |
dc.subject | ARYL BROMIDES | - |
dc.subject | VINYL ARENES | - |
dc.subject | CYCLOMETALATION | - |
dc.subject | ACTIVATION | - |
dc.subject | LIGANDS | - |
dc.subject | HYDROARYLATION | - |
dc.title | Rhodium-catalyzed selective C-H functionalization of NNN tridentate chelating compounds via a rollover pathway | - |
dc.type | Article | - |
dc.identifier.wosid | 000370573400018 | - |
dc.identifier.scopusid | 2-s2.0-84958214452 | - |
dc.type.rims | ART | - |
dc.citation.volume | 52 | - |
dc.citation.issue | 15 | - |
dc.citation.beginningpage | 3159 | - |
dc.citation.endingpage | 3162 | - |
dc.citation.publicationname | CHEMICAL COMMUNICATIONS | - |
dc.identifier.doi | 10.1039/c5cc09960a | - |
dc.contributor.localauthor | Chang, Sukbok | - |
dc.type.journalArticle | Article | - |
dc.subject.keywordPlus | TERPYRIDINE-METAL-COMPLEXES | - |
dc.subject.keywordPlus | BOND FUNCTIONALIZATION | - |
dc.subject.keywordPlus | HETEROAROMATIC-COMPOUNDS | - |
dc.subject.keywordPlus | DIRECT ARYLATION | - |
dc.subject.keywordPlus | ARYL BROMIDES | - |
dc.subject.keywordPlus | VINYL ARENES | - |
dc.subject.keywordPlus | CYCLOMETALATION | - |
dc.subject.keywordPlus | ACTIVATION | - |
dc.subject.keywordPlus | LIGANDS | - |
dc.subject.keywordPlus | HYDROARYLATION | - |
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