Rhodium-catalyzed selective C-H functionalization of NNN tridentate chelating compounds via a rollover pathway

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dc.contributor.authorHong, Seung Younko
dc.contributor.authorKwak, Jaesungko
dc.contributor.authorChang, Sukbokko
dc.date.accessioned2016-05-16T08:46:55Z-
dc.date.available2016-05-16T08:46:55Z-
dc.date.created2016-03-14-
dc.date.created2016-03-14-
dc.date.issued2016-
dc.identifier.citationCHEMICAL COMMUNICATIONS, v.52, no.15, pp.3159 - 3162-
dc.identifier.issn1359-7345-
dc.identifier.urihttp://hdl.handle.net/10203/207443-
dc.description.abstractReported herein is the first example of the Rh(NHC)-catalyzed selective bis C-H alkylation of NNN tridentate chelating compounds in reaction with alkenes. The observed excellent site-selectivity can readily be explained by the postulated rollover pathway in the C-H bond activation step. The reaction is highly facile affording bis-alkylated tridentate products in high yields over a broad range of versatile heteroarene substrates and alkene reactants including ethylene gas, thus enabling its applications to be feasible in coordination and synthetic chemistry.-
dc.languageEnglish-
dc.publisherROYAL SOC CHEMISTRY-
dc.subjectTERPYRIDINE-METAL-COMPLEXES-
dc.subjectBOND FUNCTIONALIZATION-
dc.subjectHETEROAROMATIC-COMPOUNDS-
dc.subjectDIRECT ARYLATION-
dc.subjectARYL BROMIDES-
dc.subjectVINYL ARENES-
dc.subjectCYCLOMETALATION-
dc.subjectACTIVATION-
dc.subjectLIGANDS-
dc.subjectHYDROARYLATION-
dc.titleRhodium-catalyzed selective C-H functionalization of NNN tridentate chelating compounds via a rollover pathway-
dc.typeArticle-
dc.identifier.wosid000370573400018-
dc.identifier.scopusid2-s2.0-84958214452-
dc.type.rimsART-
dc.citation.volume52-
dc.citation.issue15-
dc.citation.beginningpage3159-
dc.citation.endingpage3162-
dc.citation.publicationnameCHEMICAL COMMUNICATIONS-
dc.identifier.doi10.1039/c5cc09960a-
dc.contributor.localauthorChang, Sukbok-
dc.type.journalArticleArticle-
dc.subject.keywordPlusTERPYRIDINE-METAL-COMPLEXES-
dc.subject.keywordPlusBOND FUNCTIONALIZATION-
dc.subject.keywordPlusHETEROAROMATIC-COMPOUNDS-
dc.subject.keywordPlusDIRECT ARYLATION-
dc.subject.keywordPlusARYL BROMIDES-
dc.subject.keywordPlusVINYL ARENES-
dc.subject.keywordPlusCYCLOMETALATION-
dc.subject.keywordPlusACTIVATION-
dc.subject.keywordPlusLIGANDS-
dc.subject.keywordPlusHYDROARYLATION-
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