Rhodium-catalyzed selective C-H functionalization of NNN tridentate chelating compounds via a rollover pathway

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Reported herein is the first example of the Rh(NHC)-catalyzed selective bis C-H alkylation of NNN tridentate chelating compounds in reaction with alkenes. The observed excellent site-selectivity can readily be explained by the postulated rollover pathway in the C-H bond activation step. The reaction is highly facile affording bis-alkylated tridentate products in high yields over a broad range of versatile heteroarene substrates and alkene reactants including ethylene gas, thus enabling its applications to be feasible in coordination and synthetic chemistry.
Publisher
ROYAL SOC CHEMISTRY
Issue Date
2016
Language
English
Article Type
Article
Keywords

TERPYRIDINE-METAL-COMPLEXES; BOND FUNCTIONALIZATION; HETEROAROMATIC-COMPOUNDS; DIRECT ARYLATION; ARYL BROMIDES; VINYL ARENES; CYCLOMETALATION; ACTIVATION; LIGANDS; HYDROARYLATION

Citation

CHEMICAL COMMUNICATIONS, v.52, no.15, pp.3159 - 3162

ISSN
1359-7345
DOI
10.1039/c5cc09960a
URI
http://hdl.handle.net/10203/207443
Appears in Collection
CH-Journal Papers(저널논문)
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