DC Field | Value | Language |
---|---|---|
dc.contributor.author | Kang, Kyungjun | ko |
dc.contributor.author | Kim, Jaewook | ko |
dc.contributor.author | Lee, Ansoo | ko |
dc.contributor.author | Kim, Woo Youn | ko |
dc.contributor.author | Kim, Hyunwoo | ko |
dc.date.accessioned | 2016-05-16T08:44:50Z | - |
dc.date.available | 2016-05-16T08:44:50Z | - |
dc.date.created | 2016-02-21 | - |
dc.date.created | 2016-02-21 | - |
dc.date.created | 2016-02-21 | - |
dc.date.issued | 2016-02 | - |
dc.identifier.citation | ORGANIC LETTERS, v.18, no.3, pp.616 - 619 | - |
dc.identifier.issn | 1523-7060 | - |
dc.identifier.uri | http://hdl.handle.net/10203/207426 | - |
dc.description.abstract | A mild and efficient dehydrative cross-coupling reaction between allylic alcohols and N-heterocycles using palladium catalysis is reported. A bicyclic bridgehead phosphoramidite (briphos) ligand together with Pd(dba)(2) is a highly efficient catalyst, and an acid additive involved in the rate-determining step promotes the catalytic cycle. The coupling reaction of allylic alcohols with N-heterocycles including imidazoles, benzimidazoles, and triazole proceeds under mild reaction conditions with high yields using Pd/briphos and pentafluorophenol. | - |
dc.language | English | - |
dc.publisher | AMER CHEMICAL SOC | - |
dc.title | Palladium-Catalyzed Dehydrative Cross-Coupling of Allylic Alcohols and N-Heterocycles Promoted by a Bicyclic Bridgehead Phosphoramidite Ligand and an Acid Additive | - |
dc.type | Article | - |
dc.identifier.wosid | 000369771800069 | - |
dc.identifier.scopusid | 2-s2.0-84957599473 | - |
dc.type.rims | ART | - |
dc.citation.volume | 18 | - |
dc.citation.issue | 3 | - |
dc.citation.beginningpage | 616 | - |
dc.citation.endingpage | 619 | - |
dc.citation.publicationname | ORGANIC LETTERS | - |
dc.identifier.doi | 10.1021/acs.orglett.6b00001 | - |
dc.contributor.localauthor | Kim, Woo Youn | - |
dc.contributor.localauthor | Kim, Hyunwoo | - |
dc.description.isOpenAccess | N | - |
dc.type.journalArticle | Article | - |
dc.subject.keywordPlus | AQUEOUS-MEDIA | - |
dc.subject.keywordPlus | BOND-CLEAVAGE | - |
dc.subject.keywordPlus | AMINO-ACID | - |
dc.subject.keywordPlus | ALLYLATION | - |
dc.subject.keywordPlus | AMINATION | - |
dc.subject.keywordPlus | SUBSTITUTION | - |
dc.subject.keywordPlus | ACTIVATION | - |
dc.subject.keywordPlus | WATER | - |
dc.subject.keywordPlus | NUCLEOPHILES | - |
dc.subject.keywordPlus | COMPLEXES | - |
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