DC Field | Value | Language |
---|---|---|
dc.contributor.author | Gwon, Donghyun | ko |
dc.contributor.author | Hwang, Heejun | ko |
dc.contributor.author | Kim, Hye Kyung | ko |
dc.contributor.author | Marder, Seth R | ko |
dc.contributor.author | Chang, Sukbok | ko |
dc.date.accessioned | 2016-04-22T07:48:58Z | - |
dc.date.available | 2016-04-22T07:48:58Z | - |
dc.date.created | 2016-01-07 | - |
dc.date.created | 2016-01-07 | - |
dc.date.issued | 2015-11 | - |
dc.identifier.citation | CHEMISTRY-A EUROPEAN JOURNAL, v.21, no.48, pp.17200 - 17204 | - |
dc.identifier.issn | 0947-6539 | - |
dc.identifier.uri | http://hdl.handle.net/10203/205726 | - |
dc.description.abstract | Described herein is the development of practical routes to 8-aminoquinolines by using readily installable and easily deprotectable amidating reagents. Two scalable procedures were optimized under RhIII-catalyzed conditions: i) the use of pre-generated chlorocarbamates and ii) a two-step one-pot process that directly employs carbamates. Both approaches are highly convenient for the gram-scale synthesis of 8-aminoquinolines under mild conditions. Facile deprotection of the synthetically versatile amidating groups was achieved under the Pd-catalyzed transfer hydrogenation conditions with simultaneous deoxygenation of quinoline N-oxides, thus yielding 8-aminoquinolines in excellent overall efficiency. | - |
dc.language | English | - |
dc.publisher | WILEY-V C H VERLAG GMBH | - |
dc.subject | H BOND ACTIVATION | - |
dc.subject | SELECTIVE FLUORESCENT SENSOR | - |
dc.subject | QUINOLINE N-OXIDES | - |
dc.subject | ONE-POT SYNTHESIS | - |
dc.subject | SEMICONDUCTING NANOPARTICLES | - |
dc.subject | DISTINGUISHING CADMIUM | - |
dc.subject | COUPLING REACTIONS | - |
dc.subject | ZINC IONS | - |
dc.subject | C-C | - |
dc.subject | FUNCTIONALIZATION | - |
dc.title | Synthesis of 8-Aminoquinolines by Using Carbamate Reagents: Facile Installation and Deprotection of Practical Amidating Groups | - |
dc.type | Article | - |
dc.identifier.wosid | 000366510900007 | - |
dc.identifier.scopusid | 2-s2.0-84954380604 | - |
dc.type.rims | ART | - |
dc.citation.volume | 21 | - |
dc.citation.issue | 48 | - |
dc.citation.beginningpage | 17200 | - |
dc.citation.endingpage | 17204 | - |
dc.citation.publicationname | CHEMISTRY-A EUROPEAN JOURNAL | - |
dc.identifier.doi | 10.1002/chem.201503511 | - |
dc.contributor.localauthor | Chang, Sukbok | - |
dc.contributor.nonIdAuthor | Kim, Hye Kyung | - |
dc.contributor.nonIdAuthor | Marder, Seth R | - |
dc.type.journalArticle | Article | - |
dc.subject.keywordAuthor | 8-aminoquinolines | - |
dc.subject.keywordAuthor | amidating reagents | - |
dc.subject.keywordAuthor | carbamates | - |
dc.subject.keywordAuthor | C-H activation | - |
dc.subject.keywordAuthor | homogeneous catalysis | - |
dc.subject.keywordAuthor | rhodium | - |
dc.subject.keywordPlus | H BOND ACTIVATION | - |
dc.subject.keywordPlus | SELECTIVE FLUORESCENT SENSOR | - |
dc.subject.keywordPlus | QUINOLINE N-OXIDES | - |
dc.subject.keywordPlus | ONE-POT SYNTHESIS | - |
dc.subject.keywordPlus | SEMICONDUCTING NANOPARTICLES | - |
dc.subject.keywordPlus | DISTINGUISHING CADMIUM | - |
dc.subject.keywordPlus | COUPLING REACTIONS | - |
dc.subject.keywordPlus | ZINC IONS | - |
dc.subject.keywordPlus | C-C | - |
dc.subject.keywordPlus | FUNCTIONALIZATION | - |
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