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College of Natural Sciences(자연과학대학)Dept. of Chemistry(화학과)CH-Journal Papers(저널논문)

cis-{Pt(NH3)(2)(L)}(2+/+) (L = Cl, H2O, NH3) binding to purines and CO: Does pi-back-donation play a role?

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dc.contributor.authorBaik, Mu-Hyunko
dc.contributor.authorFriesner, RAko
dc.contributor.authorLippard, SJko
dc.date.accessioned2016-04-12T07:46:40Z-
dc.date.available2016-04-12T07:46:40Z-
dc.date.created2015-09-11-
dc.date.created2015-09-11-
dc.date.issued2003-12-
dc.identifier.citationINORGANIC CHEMISTRY, v.42, no.26, pp.8615 - 8617-
dc.identifier.issn0020-1669-
dc.identifier.urihttp://hdl.handle.net/10203/203362-
dc.description.abstractThe ability of cis-{Pt(NH3)(2)(L)}(2+/+), a molecular fragment of the anticancer drug cisplatin, to bind to purines and CO by pi-back-donation from Pt to the ligand was examined computationally. Optimized geometries and computed vibrational frequencies suggest that cis-{Pt(NH3)(2)(L)}(2+/+) (L = Cl, H2O, NH3) is a poor g-donor and that pi-back-donation does not play an important role for Pt(II)-ligand interactions in general.-
dc.languageEnglish-
dc.publisherAMER CHEMICAL SOC-
dc.subjectNONCLASSICAL METAL-CARBONYLS-
dc.subjectINTRASTRAND CROSS-LINK-
dc.subjectAB-INITIO-
dc.subjectVIBRATIONAL SPECTRA-
dc.subjectSTRETCHING REGION-
dc.subjectCISPLATIN BINDING-
dc.subjectINFRARED SPECTRA-
dc.subjectMAJOR ADDUCT-
dc.subjectDNA-ADDUCTS-
dc.subjectGUANINE-
dc.titlecis-{Pt(NH3)(2)(L)}(2+/+) (L = Cl, H2O, NH3) binding to purines and CO: Does pi-back-donation play a role?-
dc.typeArticle-
dc.identifier.wosid000187740100006-
dc.identifier.scopusid2-s2.0-0347594104-
dc.type.rimsART-
dc.citation.volume42-
dc.citation.issue26-
dc.citation.beginningpage8615-
dc.citation.endingpage8617-
dc.citation.publicationnameINORGANIC CHEMISTRY-
dc.identifier.doi10.1021/ic035022b-
dc.contributor.localauthorBaik, Mu-Hyun-
dc.contributor.nonIdAuthorFriesner, RA-
dc.contributor.nonIdAuthorLippard, SJ-
dc.type.journalArticleArticle-
dc.subject.keywordPlusNONCLASSICAL METAL-CARBONYLS-
dc.subject.keywordPlusINTRASTRAND CROSS-LINK-
dc.subject.keywordPlusAB-INITIO-
dc.subject.keywordPlusVIBRATIONAL SPECTRA-
dc.subject.keywordPlusSTRETCHING REGION-
dc.subject.keywordPlusCISPLATIN BINDING-
dc.subject.keywordPlusINFRARED SPECTRA-
dc.subject.keywordPlusMAJOR ADDUCT-
dc.subject.keywordPlusDNA-ADDUCTS-
dc.subject.keywordPlusGUANINE-
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CH-Journal Papers(저널논문)
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