alpha,beta-(C-C-C) Agostic bonds in transition metal based olefin metathesis catalyses
An alpha,beta-(C - C - C) agostic bond is found to provide the additional stabilization needed to make the formally 14-electron metallacyclobutane intermediate lower in energy than its 16-electron alkylidene analogue during olefin metathesis catalysis.
- Publisher
- ROYAL SOC CHEMISTRY
- Issue Date
- 2005
- Language
- English
- Article Type
- Article
- Keywords
RUTHENIUM CARBENE COMPLEXES; ALKYLIDENE COMPLEXES; MECHANISM; LIGANDS; POLYMERIZATION; SYSTEMS; CHOICE
- Citation
DALTON TRANSACTIONS, no.18, pp.2982 - 2984
- ISSN
- 1477-9226
- Appears in Collection
- CH-Journal Papers(저널논문)
- Files in This Item
- There are no files associated with this item.
This item is cited by other documents in WoS
| ⊙ Detail Information in WoSⓡ | Click to see |  |
| ⊙ Cited 42 items in WoS | Click to see citing articles in |  |
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.