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College of Natural Sciences(자연과학대학)Dept. of Chemistry(화학과)CH-Journal Papers(저널논문)

Computationally Designed and Experimentally Confirmed Diastereoselective Rhodium-Catalyzed Pauson-Khand Reaction at Room Temperature

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dc.contributor.authorBaik, Mu-Hyunko
dc.contributor.authorMazumder, Shivnathko
dc.contributor.authorRicci, Paoloko
dc.contributor.authorSawyer, James R.ko
dc.contributor.authorSong, Ye-Geunko
dc.contributor.authorWang, Huijunko
dc.contributor.authorEvans, P. Andrewko
dc.date.accessioned2016-04-12T07:36:48Z-
dc.date.available2016-04-12T07:36:48Z-
dc.date.created2015-09-11-
dc.date.created2015-09-11-
dc.date.issued2011-05-
dc.identifier.citationJOURNAL OF THE AMERICAN CHEMICAL SOCIETY, v.133, no.20, pp.7621 - 7623-
dc.identifier.issn0002-7863-
dc.identifier.urihttp://hdl.handle.net/10203/203310-
dc.description.abstractThe computational analysis of the rhodium-catalyzed Pauson-Khand reaction indicates that the key transition state is highly charge-polarized, wherein different diastereoisomers have distinctively different charge polarization patterns. Experimental studies demonstrate that chloro-enynes provide the optimal sigma-electron-withdrawing group to promote polarization and thereby reduce the activation barrier to provide a highly diastereoselective reaction at room temperature.-
dc.languageEnglish-
dc.publisherAMER CHEMICAL SOC-
dc.subjectCASCADE REACTIONS-
dc.subjectALKYNYL HALIDES-
dc.subjectDENSITY-
dc.subjectMECHANISM-
dc.subjectVINYLCYCLOPROPANES-
dc.subjectCYCLOADDITION-
dc.subjectEXCHANGE-
dc.subjectCO-
dc.titleComputationally Designed and Experimentally Confirmed Diastereoselective Rhodium-Catalyzed Pauson-Khand Reaction at Room Temperature-
dc.typeArticle-
dc.identifier.wosid000291580400001-
dc.identifier.scopusid2-s2.0-79957736107-
dc.type.rimsART-
dc.citation.volume133-
dc.citation.issue20-
dc.citation.beginningpage7621-
dc.citation.endingpage7623-
dc.citation.publicationnameJOURNAL OF THE AMERICAN CHEMICAL SOCIETY-
dc.identifier.doi10.1021/ja107895g-
dc.contributor.localauthorBaik, Mu-Hyun-
dc.contributor.nonIdAuthorMazumder, Shivnath-
dc.contributor.nonIdAuthorRicci, Paolo-
dc.contributor.nonIdAuthorSawyer, James R.-
dc.contributor.nonIdAuthorSong, Ye-Geun-
dc.contributor.nonIdAuthorWang, Huijun-
dc.contributor.nonIdAuthorEvans, P. Andrew-
dc.type.journalArticleArticle-
dc.subject.keywordPlusCASCADE REACTIONS-
dc.subject.keywordPlusALKYNYL HALIDES-
dc.subject.keywordPlusDENSITY-
dc.subject.keywordPlusMECHANISM-
dc.subject.keywordPlusVINYLCYCLOPROPANES-
dc.subject.keywordPlusCYCLOADDITION-
dc.subject.keywordPlusEXCHANGE-
dc.subject.keywordPlusCO-
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