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College of Natural Sciences(자연과학대학)Dept. of Chemistry(화학과)CH-Journal Papers(저널논문)

Room Temperature Dehydrogenation of Ethane to Ethylene

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dc.contributor.authorCavaliere, Vincent N.ko
dc.contributor.authorCrestani, Marco G.ko
dc.contributor.authorPinter, Balazsko
dc.contributor.authorPink, Marenko
dc.contributor.authorChen, Chun-Hsingko
dc.contributor.authorBaik, Mu-Hyunko
dc.contributor.authorMindiola, Daniel J.ko
dc.date.accessioned2016-04-12T07:36:36Z-
dc.date.available2016-04-12T07:36:36Z-
dc.date.created2015-09-11-
dc.date.created2015-09-11-
dc.date.issued2011-07-
dc.identifier.citationJOURNAL OF THE AMERICAN CHEMICAL SOCIETY, v.133, no.28, pp.10700 - 10703-
dc.identifier.issn0002-7863-
dc.identifier.urihttp://hdl.handle.net/10203/203308-
dc.description.abstractThe transient titanium alkylidyne, (PNP)Ti (CBu)-Bu-t (PNP = N[2-(PPr2)-Pr-i-4-methylphenyl](2)(-)), activates a C-H bond of ethane at room temperature, and a beta-hydrogen of the resulting ethyl ligand is subsequently transferred to the adjacent alkylidene ligand to form an ethylene adduct of titanium. Treatment of the ethylene complex with two-electron oxidants such as organic azides results in extrusion of ethene concomitant with formation of a mononuclear titanium imido complex.-
dc.languageEnglish-
dc.publisherAMER CHEMICAL SOC-
dc.subjectH BOND ACTIVATION-
dc.subjectALKANE DEHYDROGENATION-
dc.subjectIRIDIUM COMPLEXES-
dc.subjectDIHYDROGEN ATMOSPHERE-
dc.subjectRHODIUM COMPLEXES-
dc.subjectALKYL CATIONS-
dc.subjectREACTIVITY-
dc.subjectTITANIUM-
dc.subjectCHEMISTRY-
dc.subjectCATALYSTS-
dc.titleRoom Temperature Dehydrogenation of Ethane to Ethylene-
dc.typeArticle-
dc.identifier.wosid000293113200007-
dc.identifier.scopusid2-s2.0-79960281090-
dc.type.rimsART-
dc.citation.volume133-
dc.citation.issue28-
dc.citation.beginningpage10700-
dc.citation.endingpage10703-
dc.citation.publicationnameJOURNAL OF THE AMERICAN CHEMICAL SOCIETY-
dc.identifier.doi10.1021/ja202316m-
dc.contributor.localauthorBaik, Mu-Hyun-
dc.contributor.nonIdAuthorCavaliere, Vincent N.-
dc.contributor.nonIdAuthorCrestani, Marco G.-
dc.contributor.nonIdAuthorPinter, Balazs-
dc.contributor.nonIdAuthorPink, Maren-
dc.contributor.nonIdAuthorChen, Chun-Hsing-
dc.contributor.nonIdAuthorMindiola, Daniel J.-
dc.type.journalArticleArticle-
dc.subject.keywordPlusH BOND ACTIVATION-
dc.subject.keywordPlusALKANE DEHYDROGENATION-
dc.subject.keywordPlusIRIDIUM COMPLEXES-
dc.subject.keywordPlusDIHYDROGEN ATMOSPHERE-
dc.subject.keywordPlusRHODIUM COMPLEXES-
dc.subject.keywordPlusALKYL CATIONS-
dc.subject.keywordPlusREACTIVITY-
dc.subject.keywordPlusTITANIUM-
dc.subject.keywordPlusCHEMISTRY-
dc.subject.keywordPlusCATALYSTS-
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CH-Journal Papers(저널논문)
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