DC Field | Value | Language |
---|---|---|
dc.contributor.author | Cavaliere, Vincent N. | ko |
dc.contributor.author | Crestani, Marco G. | ko |
dc.contributor.author | Pinter, Balazs | ko |
dc.contributor.author | Pink, Maren | ko |
dc.contributor.author | Chen, Chun-Hsing | ko |
dc.contributor.author | Baik, Mu-Hyun | ko |
dc.contributor.author | Mindiola, Daniel J. | ko |
dc.date.accessioned | 2016-04-12T07:36:36Z | - |
dc.date.available | 2016-04-12T07:36:36Z | - |
dc.date.created | 2015-09-11 | - |
dc.date.created | 2015-09-11 | - |
dc.date.issued | 2011-07 | - |
dc.identifier.citation | JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, v.133, no.28, pp.10700 - 10703 | - |
dc.identifier.issn | 0002-7863 | - |
dc.identifier.uri | http://hdl.handle.net/10203/203308 | - |
dc.description.abstract | The transient titanium alkylidyne, (PNP)Ti (CBu)-Bu-t (PNP = N[2-(PPr2)-Pr-i-4-methylphenyl](2)(-)), activates a C-H bond of ethane at room temperature, and a beta-hydrogen of the resulting ethyl ligand is subsequently transferred to the adjacent alkylidene ligand to form an ethylene adduct of titanium. Treatment of the ethylene complex with two-electron oxidants such as organic azides results in extrusion of ethene concomitant with formation of a mononuclear titanium imido complex. | - |
dc.language | English | - |
dc.publisher | AMER CHEMICAL SOC | - |
dc.subject | H BOND ACTIVATION | - |
dc.subject | ALKANE DEHYDROGENATION | - |
dc.subject | IRIDIUM COMPLEXES | - |
dc.subject | DIHYDROGEN ATMOSPHERE | - |
dc.subject | RHODIUM COMPLEXES | - |
dc.subject | ALKYL CATIONS | - |
dc.subject | REACTIVITY | - |
dc.subject | TITANIUM | - |
dc.subject | CHEMISTRY | - |
dc.subject | CATALYSTS | - |
dc.title | Room Temperature Dehydrogenation of Ethane to Ethylene | - |
dc.type | Article | - |
dc.identifier.wosid | 000293113200007 | - |
dc.identifier.scopusid | 2-s2.0-79960281090 | - |
dc.type.rims | ART | - |
dc.citation.volume | 133 | - |
dc.citation.issue | 28 | - |
dc.citation.beginningpage | 10700 | - |
dc.citation.endingpage | 10703 | - |
dc.citation.publicationname | JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | - |
dc.identifier.doi | 10.1021/ja202316m | - |
dc.contributor.localauthor | Baik, Mu-Hyun | - |
dc.contributor.nonIdAuthor | Cavaliere, Vincent N. | - |
dc.contributor.nonIdAuthor | Crestani, Marco G. | - |
dc.contributor.nonIdAuthor | Pinter, Balazs | - |
dc.contributor.nonIdAuthor | Pink, Maren | - |
dc.contributor.nonIdAuthor | Chen, Chun-Hsing | - |
dc.contributor.nonIdAuthor | Mindiola, Daniel J. | - |
dc.type.journalArticle | Article | - |
dc.subject.keywordPlus | H BOND ACTIVATION | - |
dc.subject.keywordPlus | ALKANE DEHYDROGENATION | - |
dc.subject.keywordPlus | IRIDIUM COMPLEXES | - |
dc.subject.keywordPlus | DIHYDROGEN ATMOSPHERE | - |
dc.subject.keywordPlus | RHODIUM COMPLEXES | - |
dc.subject.keywordPlus | ALKYL CATIONS | - |
dc.subject.keywordPlus | REACTIVITY | - |
dc.subject.keywordPlus | TITANIUM | - |
dc.subject.keywordPlus | CHEMISTRY | - |
dc.subject.keywordPlus | CATALYSTS | - |
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