DC Field | Value | Language |
---|---|---|
dc.contributor.author | Tran, Ba L. | ko |
dc.contributor.author | Pinter, Balazs | ko |
dc.contributor.author | Nichols, Adam J. | ko |
dc.contributor.author | Konopka, Felicia T. | ko |
dc.contributor.author | Thompson, Rick | ko |
dc.contributor.author | Chen, Chun-Hsing | ko |
dc.contributor.author | Krzystek, J. | ko |
dc.contributor.author | Ozarowski, Andrew | ko |
dc.contributor.author | Telser, Joshua | ko |
dc.contributor.author | Baik, Mu-Hyun | ko |
dc.contributor.author | Meyer, Karsten | ko |
dc.contributor.author | Mindiola, Daniel J. | ko |
dc.date.accessioned | 2016-04-12T07:30:04Z | - |
dc.date.available | 2016-04-12T07:30:04Z | - |
dc.date.created | 2015-09-11 | - |
dc.date.created | 2015-09-11 | - |
dc.date.issued | 2012-08 | - |
dc.identifier.citation | JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, v.134, no.31, pp.13035 - 13045 | - |
dc.identifier.issn | 0002-7863 | - |
dc.identifier.uri | http://hdl.handle.net/10203/203302 | - |
dc.description.abstract | We report the first mononuclear three-coordinate vanadium(II) complex [(nacnac)V(ODiiP)] and its activation of N-2 to form an end-on bridging dinitrogen complex with a topologically linear V(III)N2V(III) core and where each vanadium center antiferromagnetically couples to give a ground state singlet with an accessible triplet state as inferred by HFEPR spectroscopy. In addition to investigating the conversion of N-2 to the terminal nitride (as well as the microscopic reverse process), we discuss its similarities and contrasts to the isovalent d(3) system, [Mo(N[Bu-t]Ar)(3)], and the S = 1 system [(Ar[Bu-t]N)(3)Mo](2)(mu(2)-eta(1):eta(1)-N-2). | - |
dc.language | English | - |
dc.publisher | AMER CHEMICAL SOC | - |
dc.subject | ELECTRON-PARAMAGNETIC-RESONANCE | - |
dc.subject | EFFECTIVE CORE POTENTIALS | - |
dc.subject | BETA-DIKETIMINATE LIGAND | - |
dc.subject | TRANSITION-METAL DIMERS | - |
dc.subject | RAY CRYSTAL-STRUCTURES | - |
dc.subject | DINITROGEN CLEAVAGE | - |
dc.subject | MOLECULAR CALCULATIONS | - |
dc.subject | REDUCTIVE CLEAVAGE | - |
dc.subject | TRIAMIDOAMINE LIGANDS | - |
dc.subject | DIAMIDOAMINE COMPLEX | - |
dc.title | A Planar Three-Coordinate Vanadium(II) Complex and the Study of Terminal Vanadium Nitrides from N-2: A Kinetic or Thermodynamic Impediment to N-N Bond Cleavage? | - |
dc.type | Article | - |
dc.identifier.wosid | 000307210900027 | - |
dc.identifier.scopusid | 2-s2.0-84864699542 | - |
dc.type.rims | ART | - |
dc.citation.volume | 134 | - |
dc.citation.issue | 31 | - |
dc.citation.beginningpage | 13035 | - |
dc.citation.endingpage | 13045 | - |
dc.citation.publicationname | JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | - |
dc.identifier.doi | 10.1021/ja303360v | - |
dc.contributor.localauthor | Baik, Mu-Hyun | - |
dc.contributor.nonIdAuthor | Tran, Ba L. | - |
dc.contributor.nonIdAuthor | Pinter, Balazs | - |
dc.contributor.nonIdAuthor | Nichols, Adam J. | - |
dc.contributor.nonIdAuthor | Konopka, Felicia T. | - |
dc.contributor.nonIdAuthor | Thompson, Rick | - |
dc.contributor.nonIdAuthor | Chen, Chun-Hsing | - |
dc.contributor.nonIdAuthor | Krzystek, J. | - |
dc.contributor.nonIdAuthor | Ozarowski, Andrew | - |
dc.contributor.nonIdAuthor | Telser, Joshua | - |
dc.contributor.nonIdAuthor | Meyer, Karsten | - |
dc.contributor.nonIdAuthor | Mindiola, Daniel J. | - |
dc.type.journalArticle | Article | - |
dc.subject.keywordPlus | ELECTRON-PARAMAGNETIC-RESONANCE | - |
dc.subject.keywordPlus | EFFECTIVE CORE POTENTIALS | - |
dc.subject.keywordPlus | BETA-DIKETIMINATE LIGAND | - |
dc.subject.keywordPlus | TRANSITION-METAL DIMERS | - |
dc.subject.keywordPlus | RAY CRYSTAL-STRUCTURES | - |
dc.subject.keywordPlus | DINITROGEN CLEAVAGE | - |
dc.subject.keywordPlus | MOLECULAR CALCULATIONS | - |
dc.subject.keywordPlus | REDUCTIVE CLEAVAGE | - |
dc.subject.keywordPlus | TRIAMIDOAMINE LIGANDS | - |
dc.subject.keywordPlus | DIAMIDOAMINE COMPLEX | - |
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