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College of Natural Sciences(자연과학대학)Dept. of Chemistry(화학과)CH-Journal Papers(저널논문)

Synthesis and Structural Characterization of Hexacoordinate Silicon, Germanium, and Titanium Complexes of the E-coli Siderophore Enterobactin

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dc.contributor.authorBaramov, Todorko
dc.contributor.authorKeijzer, Karlijnko
dc.contributor.authorIrran, Elisabethko
dc.contributor.authorMoesker, Evako
dc.contributor.authorBaik, Mu-Hyunko
dc.contributor.authorSuessmuth, Roderichko
dc.date.accessioned2016-04-12T07:29:25Z-
dc.date.available2016-04-12T07:29:25Z-
dc.date.created2015-09-11-
dc.date.created2015-09-11-
dc.date.issued2013-08-
dc.identifier.citationCHEMISTRY-A EUROPEAN JOURNAL, v.19, no.32, pp.10536 - 10542-
dc.identifier.issn0947-6539-
dc.identifier.urihttp://hdl.handle.net/10203/203296-
dc.description.abstractThe E. coli siderophore enterobactin, one of the strongest Fe-III chelators known to date, is also capable of binding Si-IV under physiological conditions. We report on the synthesis and structural characterization of the tris(catecholate) Si-IV-enterobactin complex and its Ge-IV and Ti-IV analogues. Comparative structural analysis, supported by quantum-chemical calculations, reveals the correlation between the ionic radius and the structural changes in enterobactin upon complexation.-
dc.languageEnglish-
dc.publisherWILEY-V C H VERLAG GMBH-
dc.subjectMICROBIAL IRON TRANSPORT-
dc.subjectCOORDINATION CHEMISTRY-
dc.subjectANALOGS-
dc.subjectENANTIOENTEROBACTIN-
dc.subjectSTABILITY-
dc.subjectLIGAND-
dc.subjectION-
dc.subjectCHIRALITY-
dc.subjectSURFACES-
dc.subjectBACTERIA-
dc.titleSynthesis and Structural Characterization of Hexacoordinate Silicon, Germanium, and Titanium Complexes of the E-coli Siderophore Enterobactin-
dc.typeArticle-
dc.identifier.wosid000322238800020-
dc.identifier.scopusid2-s2.0-84880964466-
dc.type.rimsART-
dc.citation.volume19-
dc.citation.issue32-
dc.citation.beginningpage10536-
dc.citation.endingpage10542-
dc.citation.publicationnameCHEMISTRY-A EUROPEAN JOURNAL-
dc.identifier.doi10.1002/chem.201301825-
dc.contributor.localauthorBaik, Mu-Hyun-
dc.contributor.nonIdAuthorBaramov, Todor-
dc.contributor.nonIdAuthorKeijzer, Karlijn-
dc.contributor.nonIdAuthorIrran, Elisabeth-
dc.contributor.nonIdAuthorMoesker, Eva-
dc.contributor.nonIdAuthorSuessmuth, Roderich-
dc.type.journalArticleArticle-
dc.subject.keywordAuthorenterobactin-
dc.subject.keywordAuthorgermanium-
dc.subject.keywordAuthorsiderophores-
dc.subject.keywordAuthorsilicon-
dc.subject.keywordAuthortitanium-
dc.subject.keywordPlusMICROBIAL IRON TRANSPORT-
dc.subject.keywordPlusCOORDINATION CHEMISTRY-
dc.subject.keywordPlusANALOGS-
dc.subject.keywordPlusENANTIOENTEROBACTIN-
dc.subject.keywordPlusSTABILITY-
dc.subject.keywordPlusLIGAND-
dc.subject.keywordPlusION-
dc.subject.keywordPlusCHIRALITY-
dc.subject.keywordPlusSURFACES-
dc.subject.keywordPlusBACTERIA-
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