Binary role of an ylide in formation of a terminal methylidene complex of niobium
The first structurally characterized niobium(V) complex possessing a terminal methylidene ligand is reported in high yield from the reaction of [(Ar'O)(2)Nb(CH3)(2)Cl] (Ar' = (2,6-CHPh2)(2)-4-tBu-C6H2) and two equivalents of H2CPPh3.
- Publisher
- ROYAL SOC CHEMISTRY
- Issue Date
- 2014
- Language
- English
- Article Type
- Article
- Keywords
METHYLENE COMPLEX; TANTALUM; DERIVATIVES; LIGAND; IMIDO; BOND; PERMETHYLTANTALOCENE; DECOMPOSITION; REACTIVITY; PRECURSOR
- Citation
CHEMICAL COMMUNICATIONS, v.50, no.47, pp.6267 - 6269
- ISSN
- 1359-7345
- Appears in Collection
- CH-Journal Papers(저널논문)
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