Synthesis of Phosphoramidates: A Facile Approach Based on the C-N Bond Formation via Ir-Catalyzed Direct C-H Amidation
A new synthetic route to phosphoramidates by intermolecular C-H amidation is presented. Substrates with assorted directing groups were activated by an iridium-based catalyst system and reacted with a number of phosphoryl azides, executing efficient phosphoramidate synthesis via C-N bond formations. (Chemical Equation Presented).
- Publisher
- AMER CHEMICAL SOC
- Issue Date
- 2014-10
- Language
- English
- Article Type
- Article
- Keywords
PHOSPHORYL AZIDES; ARYL AZIDES; CONVENIENT SYNTHESIS; 1,2-AMINO ALCOHOLS; MASS-SPECTROMETRY; FORMING REACTIONS; FLAME-RETARDANT; NITROGEN-SOURCE; ACTIVATION; AMINATION
- Citation
ORGANIC LETTERS, v.16, no.20, pp.5466 - 5469
- ISSN
- 1523-7060
- Appears in Collection
- CH-Journal Papers(저널논문)
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