Bis(η5-Pentamethylcyclopentadienyl) Complexes of Molybdenum

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dc.contributor.authorShin, Jun Hoko
dc.contributor.authorChurchill, David Gko
dc.contributor.authorParkin, Gerardko
dc.contributor.authorRoggan, Stefanko
dc.contributor.authorJankowski, Christelko
dc.contributor.authorLimberg, Christianko
dc.contributor.authorTonks, Ianko
dc.contributor.authorBercaw, Johnko
dc.date.accessioned2015-06-24T02:17:58Z-
dc.date.available2015-06-24T02:17:58Z-
dc.date.created2015-06-10-
dc.date.created2015-06-10-
dc.date.created2015-06-10-
dc.date.created2015-06-10-
dc.date.issued2014-05-
dc.identifier.citationInorganic Syntheses, v.36, pp.58 - 62-
dc.identifier.urihttp://hdl.handle.net/10203/198974-
dc.description.abstractMolybdenocene and tungstenocene complexes have played a prominent role in the development of organometallic chemistry. This chapter describes the synthesis of (η5-C5Me5)2MoCl2 and (η5-C5Me5)2MoH2. (η5-C5Me5)2MoCl2 is obtained by a two-step sequence involving (i) the reaction of MoCl5 with a mixture of KC5Me5 and NaBH4 to give crude (η5-C5Me5)2MoH2, followed by (ii) addition of CHCl3. (η5-C5Me5)2MoCl2 is a useful precursor for a variety of other permethylmolybdenocene derivatives, which include hydride, alkyl, carbonyl, and oxo complexes.-
dc.languageEnglish-
dc.publisherWiley Blackwell-
dc.titleBis(η5-Pentamethylcyclopentadienyl) Complexes of Molybdenum-
dc.typeArticle-
dc.identifier.scopusid2-s2.0-84927684754-
dc.type.rimsART-
dc.citation.volume36-
dc.citation.beginningpage58-
dc.citation.endingpage62-
dc.citation.publicationnameInorganic Syntheses-
dc.identifier.doi10.1002/9781118744994.ch12-
dc.contributor.localauthorChurchill, David G-
dc.contributor.nonIdAuthorShin, Jun Ho-
dc.contributor.nonIdAuthorParkin, Gerard-
dc.contributor.nonIdAuthorRoggan, Stefan-
dc.contributor.nonIdAuthorJankowski, Christel-
dc.contributor.nonIdAuthorLimberg, Christian-
dc.contributor.nonIdAuthorTonks, Ian-
dc.contributor.nonIdAuthorBercaw, John-
dc.description.isOpenAccessY-
dc.subject.keywordAuthorBis(pentamethylcyclopentadienyl) dichloromolybdenum(IV)-
dc.subject.keywordAuthorBis(pentamethylcyclopentadienyl) dihydridomolybdenum(IV)-
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CH-Journal Papers(저널논문)
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