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College of Natural Sciences(자연과학대학)Dept. of Chemistry(화학과)CH-Journal Papers(저널논문)

Selective Cyclization of Arylnitrones to Indolines under External Oxidant-Free Conditions: Dual Role of Rh(III) Catalyst in the C-H Activation and Oxygen Atom Transfer

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dc.contributor.authorDateer, Ramesh B.ko
dc.contributor.authorChang, Suk-Bokko
dc.date.accessioned2015-06-04T05:49:04Z-
dc.date.available2015-06-04T05:49:04Z-
dc.date.created2015-06-01-
dc.date.created2015-06-01-
dc.date.created2015-06-01-
dc.date.issued2015-04-
dc.identifier.citationJOURNAL OF THE AMERICAN CHEMICAL SOCIETY, v.137, no.15, pp.4908 - 4911-
dc.identifier.issn0002-7863-
dc.identifier.urihttp://hdl.handle.net/10203/198786-
dc.description.abstractThe first example of Rh(III)-catalyzed cyclization of arylnitrones to indolines under external oxidant-free conditions is presented. An intermolecular coupling of arylnitrones with internal alkynes is made possible by the dual role of the Cp*Rh(III) catalyst mediating both the C-H bond activation and O-atom transfer. Synthetically important and pharmacologically privileged indoline derivatives were obtained in good yields with high diastereoselectivity.-
dc.languageEnglish-
dc.publisherAMER CHEMICAL SOC-
dc.subjectQUINOLINE N-OXIDES-
dc.subjectBOND FUNCTIONALIZATION-
dc.subjectRHODIUM CATALYSIS-
dc.subjectSTEREOSELECTIVE-SYNTHESIS-
dc.subjectDIRECTING GROUP-
dc.subjectALKYNES-
dc.subjectNITRONES-
dc.subjectPALLADIUM-
dc.subjectCYCLOADDITION-
dc.subjectINDOLES-
dc.titleSelective Cyclization of Arylnitrones to Indolines under External Oxidant-Free Conditions: Dual Role of Rh(III) Catalyst in the C-H Activation and Oxygen Atom Transfer-
dc.typeArticle-
dc.identifier.wosid000353606700009-
dc.identifier.scopusid2-s2.0-84928494419-
dc.type.rimsART-
dc.citation.volume137-
dc.citation.issue15-
dc.citation.beginningpage4908-
dc.citation.endingpage4911-
dc.citation.publicationnameJOURNAL OF THE AMERICAN CHEMICAL SOCIETY-
dc.identifier.doi10.1021/jacs.5b01065-
dc.contributor.localauthorChang, Suk-Bok-
dc.contributor.nonIdAuthorDateer, Ramesh B.-
dc.type.journalArticleArticle-
dc.subject.keywordPlusQUINOLINE N-OXIDES-
dc.subject.keywordPlusBOND FUNCTIONALIZATION-
dc.subject.keywordPlusRHODIUM CATALYSIS-
dc.subject.keywordPlusSTEREOSELECTIVE-SYNTHESIS-
dc.subject.keywordPlusDIRECTING GROUP-
dc.subject.keywordPlusALKYNES-
dc.subject.keywordPlusNITRONES-
dc.subject.keywordPlusPALLADIUM-
dc.subject.keywordPlusCYCLOADDITION-
dc.subject.keywordPlusINDOLES-
dc.subject.keywordPlusQUINOLINE N-OXIDES-
dc.subject.keywordPlusBOND FUNCTIONALIZATION-
dc.subject.keywordPlusRHODIUM CATALYSIS-
dc.subject.keywordPlusSTEREOSELECTIVE-SYNTHESIS-
dc.subject.keywordPlusDIRECTING GROUP-
dc.subject.keywordPlusALKYNES-
dc.subject.keywordPlusNITRONES-
dc.subject.keywordPlusPALLADIUM-
dc.subject.keywordPlusCYCLOADDITION-
dc.subject.keywordPlusINDOLES-
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CH-Journal Papers(저널논문)
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