DC Field | Value | Language |
---|---|---|
dc.contributor.author | Kim, Yeong-Eun | ko |
dc.contributor.author | Kim, Jin | ko |
dc.contributor.author | Lee, Yunho | ko |
dc.date.accessioned | 2015-03-26T08:44:22Z | - |
dc.date.available | 2015-03-26T08:44:22Z | - |
dc.date.created | 2014-09-23 | - |
dc.date.created | 2014-09-23 | - |
dc.date.issued | 2014-10 | - |
dc.identifier.citation | CHEMICAL COMMUNICATIONS, v.50, no.78, pp.11458 - 11461 | - |
dc.identifier.issn | 1359-7345 | - |
dc.identifier.uri | http://hdl.handle.net/10203/194182 | - |
dc.description.abstract | An uncommon nickel dinitrogen adduct and its tendency toward CO2 binding are investigated using a ((PPP)-P-Me)Ni scaffold. ((PPP)-P-Me)Ni(N-2) (1) and {((PPP)-P-Me)Ni}(2)(mu-N-2) (2) were prepared and their treatment with CO2 revealed the formation of ((PPP)-P-Me)Ni(eta(2)-CO2) (3). This is a new type of CO2 binding for a zero-valent nickel center supported by three donor ligands, reminiscent of the CODH active site environment. Clear unique structural differences in 3 are evident when compared with previous 4-coordinate Ni-CO2 adducts. Compound 3 when treated with B(C6F5)(3) gives the Lewis acid-base adduct ((PPP)-P-Me)Ni{COOB(C6F5)(3)} (4) possessing a Ni-mu-CO2-kappa C-2, O-B moiety. | - |
dc.language | English | - |
dc.publisher | ROYAL SOC CHEMISTRY | - |
dc.subject | MONOXIDE DEHYDROGENASE | - |
dc.subject | MOLECULAR-STRUCTURE | - |
dc.subject | DINITROGEN COMPLEX | - |
dc.subject | CO2 | - |
dc.subject | ACTIVATION | - |
dc.subject | CHEMISTRY | - |
dc.subject | REACTIVITY | - |
dc.subject | CORE | - |
dc.subject | NI | - |
dc.title | Formation of a nickel carbon dioxide adduct and its transformation mediated by a Lewis acid | - |
dc.type | Article | - |
dc.identifier.wosid | 000341774200004 | - |
dc.identifier.scopusid | 2-s2.0-84922373662 | - |
dc.type.rims | ART | - |
dc.citation.volume | 50 | - |
dc.citation.issue | 78 | - |
dc.citation.beginningpage | 11458 | - |
dc.citation.endingpage | 11461 | - |
dc.citation.publicationname | CHEMICAL COMMUNICATIONS | - |
dc.identifier.doi | 10.1039/c4cc04800h | - |
dc.contributor.localauthor | Lee, Yunho | - |
dc.type.journalArticle | Article | - |
dc.subject.keywordPlus | MONOXIDE DEHYDROGENASE | - |
dc.subject.keywordPlus | MOLECULAR-STRUCTURE | - |
dc.subject.keywordPlus | DINITROGEN COMPLEX | - |
dc.subject.keywordPlus | CO2 | - |
dc.subject.keywordPlus | ACTIVATION | - |
dc.subject.keywordPlus | CHEMISTRY | - |
dc.subject.keywordPlus | REACTIVITY | - |
dc.subject.keywordPlus | CORE | - |
dc.subject.keywordPlus | NI | - |
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