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College of Natural Sciences(자연과학대학)Dept. of Chemistry(화학과)CH-Journal Papers(저널논문)

Bicyclic Bridgehead Phosphoramidite (Briphos) Ligands with Tunable π-Acceptor Ability and Catalytic Activity in the Rhodium-Catalyzed Conjugate Additions

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dc.contributor.authorLee, An Sooko
dc.contributor.authorAhn, Seihwanko
dc.contributor.authorKang, KyungJunko
dc.contributor.authorSeo, Min Seobko
dc.contributor.authorKim, Yeon Joonko
dc.contributor.authorKim, Woo-Younko
dc.contributor.authorKim, Hyunwooko
dc.date.accessioned2015-01-29T07:33:01Z-
dc.date.available2015-01-29T07:33:01Z-
dc.date.created2014-12-26-
dc.date.created2014-12-26-
dc.date.created2014-12-26-
dc.date.created2014-12-26-
dc.date.issued2014-10-
dc.identifier.citationORGANIC LETTERS, v.16, no.20, pp.5490 - 5493-
dc.identifier.issn1523-7060-
dc.identifier.urihttp://hdl.handle.net/10203/193928-
dc.description.abstractA new type of bicyclic bridgehead phosphoramidites (briphos) is reported, where the geometrical constraints significantly enhance the π-acceptor ability compared with its monocyclic analogs. The briphos is shown to be highly efficient and tunable for Rh(I)-catalyzed conjugate additions of aryl boronic acids to α,β-unsaturated ketones and N-tosyl ketimines. (Chemical Equation Presented).-
dc.languageEnglish-
dc.publisherAMER CHEMICAL SOC-
dc.titleBicyclic Bridgehead Phosphoramidite (Briphos) Ligands with Tunable π-Acceptor Ability and Catalytic Activity in the Rhodium-Catalyzed Conjugate Additions-
dc.typeArticle-
dc.identifier.wosid000363220800007-
dc.identifier.scopusid2-s2.0-84908068458-
dc.type.rimsART-
dc.citation.volume16-
dc.citation.issue20-
dc.citation.beginningpage5490-
dc.citation.endingpage5493-
dc.citation.publicationnameORGANIC LETTERS-
dc.identifier.doi10.1021/ol502772m-
dc.contributor.localauthorKim, Woo-Youn-
dc.contributor.localauthorKim, Hyunwoo-
dc.description.isOpenAccessN-
dc.type.journalArticleArticle-
dc.subject.keywordPlusTRANSITION-METAL-COMPLEXES-
dc.subject.keywordPlusN-SULFONYL KETIMINES-
dc.subject.keywordPlusROOM-TEMPERATURE-
dc.subject.keywordPlusASYMMETRIC 1,4-ADDITION-
dc.subject.keywordPlusCOORDINATION CHEMISTRY-
dc.subject.keywordPlusARYLBORONIC ACIDS-
dc.subject.keywordPlusHELICAL CHIRALITY-
dc.subject.keywordPlusTOSYL KETIMINES-
dc.subject.keywordPlusARYLATION-
dc.subject.keywordPlusARYL-
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