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College of Natural Sciences(자연과학대학)Dept. of Chemistry(화학과)CH-Journal Papers(저널논문)

A highly Lewis-acidic Pd(IV) surface on Pd@SiO2 nanocatalysts for hydroalkoxylation reactions

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dc.contributor.authorKim, Mijongko
dc.contributor.authorLee, Suyeonko
dc.contributor.authorKim, Kiseongko
dc.contributor.authorShin, Dongwooko
dc.contributor.authorKim, Hyunwooko
dc.contributor.authorSong, Hyun-Joonko
dc.date.accessioned2015-01-29T07:23:22Z-
dc.date.available2015-01-29T07:23:22Z-
dc.date.created2014-11-20-
dc.date.created2014-11-20-
dc.date.created2014-11-20-
dc.date.issued2014-12-
dc.identifier.citationCHEMICAL COMMUNICATIONS, v.50, no.95, pp.14938 - 14941-
dc.identifier.issn1359-7345-
dc.identifier.urihttp://hdl.handle.net/10203/193886-
dc.description.abstractThe Pd(IV) species, known to be critical intermediates in homogeneous catalysis, were successfully generated on the surface of Pd nanocatalysts via oxidation with iodobenzene dichloride (PhICl2) or N-chlorosuccinimide (NCS). In particular, the Pd@SiO2 yolk-shell nanocatalyst activated by PhICl2 showed high reactivity and superior stability to the other Pd-based catalysts for hydroalkoxylation reactions even at 25 degrees C.-
dc.languageEnglish-
dc.publisherROYAL SOC CHEMISTRY-
dc.titleA highly Lewis-acidic Pd(IV) surface on Pd@SiO2 nanocatalysts for hydroalkoxylation reactions-
dc.typeArticle-
dc.identifier.wosid000344596700003-
dc.identifier.scopusid2-s2.0-84908611631-
dc.type.rimsART-
dc.citation.volume50-
dc.citation.issue95-
dc.citation.beginningpage14938-
dc.citation.endingpage14941-
dc.citation.publicationnameCHEMICAL COMMUNICATIONS-
dc.identifier.doi10.1039/c4cc05112b-
dc.contributor.localauthorKim, Hyunwoo-
dc.contributor.localauthorSong, Hyun-Joon-
dc.contributor.nonIdAuthorLee, Suyeon-
dc.contributor.nonIdAuthorShin, Dongwoo-
dc.description.isOpenAccessN-
dc.type.journalArticleArticle-
dc.subject.keywordPlusYOLK-SHELL NANOCATALYSTS-
dc.subject.keywordPlusCROSS-COUPLING REACTIONS-
dc.subject.keywordPlusHETEROGENEOUS CATALYSIS-
dc.subject.keywordPlusNANOPARTICLES-
dc.subject.keywordPlusSELECTIVITY-
dc.subject.keywordPlusSHAPE-
dc.subject.keywordPlusNANOSCIENCE-
dc.subject.keywordPlusREACTIVITY-
dc.subject.keywordPlusSTABILITY-
dc.subject.keywordPlusCHEMISTRY-
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CH-Journal Papers(저널논문)
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