[P6Se12](4-): A phosphorus-rich selenophosphate with low-valent P centers

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dc.contributor.authorChung, Inko
dc.contributor.authorKarst, ALko
dc.contributor.authorWeliky, DPko
dc.contributor.authorKanatzidis, MGko
dc.date.accessioned2014-12-16T01:04:43Z-
dc.date.available2014-12-16T01:04:43Z-
dc.date.created2014-10-20-
dc.date.created2014-10-20-
dc.date.issued2006-04-
dc.identifier.citationINORGANIC CHEMISTRY, v.45, no.7, pp.2785 - 2787-
dc.identifier.issn0020-1669-
dc.identifier.urihttp://hdl.handle.net/10203/192743-
dc.description.abstractThe new selenophosphate Rb4P6Se12 features the trans-decalin-like, [P6Se12](4-) anion, a phosphorus-rich species that possesses three parallel P-P bonds and formally p(2+) and P4+ centers. The synthesis of Rb(4)P(6)Sel(2) was accomplished with the reductive addition of P to RbPSe6 and represents an interesting example of how alkali chalcophosphates can serve as starting materials to produce new compounds under mild reaction conditions.-
dc.languageEnglish-
dc.publisherAMER CHEMICAL SOC-
dc.subjectCRYSTAL-STRUCTURE-
dc.subjectFLUX-
dc.subjectRB-
dc.subjectCHALCOGENIDES-
dc.subjectTHIOPHOSPHATE-
dc.subjectCHEMISTRY-
dc.subjectCHAINS-
dc.subjectANION-
dc.title[P6Se12](4-): A phosphorus-rich selenophosphate with low-valent P centers-
dc.typeArticle-
dc.identifier.wosid000236476700006-
dc.type.rimsART-
dc.citation.volume45-
dc.citation.issue7-
dc.citation.beginningpage2785-
dc.citation.endingpage2787-
dc.citation.publicationnameINORGANIC CHEMISTRY-
dc.identifier.doi10.1021/ic0601135-
dc.contributor.localauthorChung, In-
dc.contributor.nonIdAuthorKarst, AL-
dc.contributor.nonIdAuthorWeliky, DP-
dc.contributor.nonIdAuthorKanatzidis, MG-
dc.type.journalArticleArticle-
dc.subject.keywordPlusCRYSTAL-STRUCTURE-
dc.subject.keywordPlusFLUX-
dc.subject.keywordPlusRB-
dc.subject.keywordPlusCHALCOGENIDES-
dc.subject.keywordPlusTHIOPHOSPHATE-
dc.subject.keywordPlusCHEMISTRY-
dc.subject.keywordPlusCHAINS-
dc.subject.keywordPlusANION-
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