[P6Se12](4-): A phosphorus-rich selenophosphate with low-valent P centers

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The new selenophosphate Rb4P6Se12 features the trans-decalin-like, [P6Se12](4-) anion, a phosphorus-rich species that possesses three parallel P-P bonds and formally p(2+) and P4+ centers. The synthesis of Rb(4)P(6)Sel(2) was accomplished with the reductive addition of P to RbPSe6 and represents an interesting example of how alkali chalcophosphates can serve as starting materials to produce new compounds under mild reaction conditions.
Publisher
AMER CHEMICAL SOC
Issue Date
2006-04
Language
English
Article Type
Article
Keywords

CRYSTAL-STRUCTURE; FLUX; RB; CHALCOGENIDES; THIOPHOSPHATE; CHEMISTRY; CHAINS; ANION

Citation

INORGANIC CHEMISTRY, v.45, no.7, pp.2785 - 2787

ISSN
0020-1669
DOI
10.1021/ic0601135
URI
http://hdl.handle.net/10203/192743
Appears in Collection
NT-Journal Papers(저널논문)
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