This paper presents a theoretical analysis, an optimal design method, and experimental results for a wireless power transfer (WPT) system with an intermediate coil. The analytical expression of the dc voltage transfer function is presented and discussed. In a two-coilWPT system, which has low coupling coefficient, the intermediate coil boosts the apparent self-inductance and magnetizing inductance of the primary side at around the resonance frequency of the intermediate coil, so that the apparent coupling coefficient is compensated. The coupling coefficient makes the system efficiency increase and induces bifurcation phenomenon. From the analysis, this paper proposes an optimal design method using the second resonance frequency operation with the bifurcation phenomenon and presents design procedure for high efficiency. A prototype of the WPT system with the intermediate coil is implemented and experimented to verify the validity of the analysis and the proposed design method. The prototype operates at 100 kHz switching frequency and has an air gap between primary and secondary side of 200 mm. An overall system efficiency of 95.57% has been achieved at 6.6 kW of output power.