Promoting effect of Ni on PdCo alloy supported on carbon for electrochemical oxygen reduction reaction

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Carbon supported Pd and Pd alloys are synthesized and characterized as cathode catalysts for the oxygen reduction reaction (ORR). Physical and electrochemical properties of the prepared catalysts are measured by XRD, TEM, EDX, XPS, and a three electrode half cell test. Pd7Co2Ni1/C catalyst shows the highest ORR activity among the Pd based catalysts and significantly higher methanol tolerance than Pt/C. It exhibits good performance in single cell operation.
Publisher
ELSEVIER SCIENCE BV
Issue Date
2014-09
Language
English
Article Type
Article; Proceedings Paper
Keywords

METHANOL FUEL-CELLS; THERMODYNAMIC GUIDELINES; BIMETALLIC CATALYSTS; ELECTROCATALYSTS; ELECTROOXIDATION; DESIGN; NANOPARTICLES; CATHODE

Citation

CATALYSIS TODAY, v.232, pp.171 - 174

ISSN
0920-5861
DOI
10.1016/j.cattod.2013.10.010
URI
http://hdl.handle.net/10203/189120
Appears in Collection
CBE-Journal Papers(저널논문)
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