Template-free synthesis of high surface area nitrogen-rich carbon microporous spheres and their hydrogen uptake capacity

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dc.contributor.authorKim, Se Yunko
dc.contributor.authorSuh, Won Hyukko
dc.contributor.authorChoi, Jung Hoonko
dc.contributor.authorYi, Yoo Sooko
dc.contributor.authorLee, Sung Keunko
dc.contributor.authorStucky, Galen D.ko
dc.contributor.authorKang, Jeung Kuko
dc.date.accessioned2014-08-29T01:29:33Z-
dc.date.available2014-08-29T01:29:33Z-
dc.date.created2014-02-17-
dc.date.created2014-02-17-
dc.date.issued2014-02-
dc.identifier.citationJOURNAL OF MATERIALS CHEMISTRY A, v.2, no.7, pp.2227 - 2232-
dc.identifier.issn2050-7488-
dc.identifier.urihttp://hdl.handle.net/10203/188761-
dc.description.abstractNitrogen-rich carbon microporous spheres (NCMSs) are synthesized for the first time by carbonizing melamine-formaldehyde spheres (MFSs). The surface area of NCMSs is increased approximately 100 times after the carbonization process. The NCMS synthetic process is facile and convenient to reproduce since the hard template production step is eliminated. In addition, the C-13 MAS NMR spectrum for the NCMSs shows that the spheres are consisting of carbon atoms with multiple sp(2) bonding configurations. Moreover, we find that nanopores in NCMSs offer high uptake capacity for hydrogen molecules.-
dc.languageEnglish-
dc.publisherROYAL SOC CHEMISTRY-
dc.subjectMELAMINE-FORMALDEHYDE RESIN-
dc.subjectMETHANOL FUEL-CELL-
dc.subjectSTORAGE MATERIALS-
dc.subjectNMR-SPECTROSCOPY-
dc.subjectACTIVATED CARBON-
dc.subjectPORE-SIZE-
dc.subjectADSORPTION-
dc.subjectNANOTUBES-
dc.subjectNITRIDE-
dc.subjectGAS-
dc.titleTemplate-free synthesis of high surface area nitrogen-rich carbon microporous spheres and their hydrogen uptake capacity-
dc.typeArticle-
dc.identifier.wosid000330048400028-
dc.identifier.scopusid2-s2.0-84892897221-
dc.type.rimsART-
dc.citation.volume2-
dc.citation.issue7-
dc.citation.beginningpage2227-
dc.citation.endingpage2232-
dc.citation.publicationnameJOURNAL OF MATERIALS CHEMISTRY A-
dc.identifier.doi10.1039/c3ta14030j-
dc.embargo.liftdate9999-12-31-
dc.embargo.terms9999-12-31-
dc.contributor.localauthorKang, Jeung Ku-
dc.contributor.nonIdAuthorSuh, Won Hyuk-
dc.contributor.nonIdAuthorYi, Yoo Soo-
dc.contributor.nonIdAuthorLee, Sung Keun-
dc.contributor.nonIdAuthorStucky, Galen D.-
dc.type.journalArticleArticle-
dc.subject.keywordPlusMELAMINE-FORMALDEHYDE RESIN-
dc.subject.keywordPlusMETHANOL FUEL-CELL-
dc.subject.keywordPlusSTORAGE MATERIALS-
dc.subject.keywordPlusNMR-SPECTROSCOPY-
dc.subject.keywordPlusACTIVATED CARBON-
dc.subject.keywordPlusPORE-SIZE-
dc.subject.keywordPlusADSORPTION-
dc.subject.keywordPlusNANOTUBES-
dc.subject.keywordPlusNITRIDE-
dc.subject.keywordPlusGAS-
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