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College of Natural Sciences(자연과학대학)Dept. of Chemistry(화학과)CH-Journal Papers(저널논문)

A Chiral meso-ABC-Corrolatochromium(V) Complex

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dc.contributor.authorEgorova, Olga A.ko
dc.contributor.authorTsay, Olga G.ko
dc.contributor.authorKhatua, Snehadrinarayanko
dc.contributor.authorHuh, Jung-Ohko
dc.contributor.authorChurchill, David Gko
dc.date.accessioned2010-05-28T04:54:50Z-
dc.date.available2010-05-28T04:54:50Z-
dc.date.created2012-02-06-
dc.date.created2012-02-06-
dc.date.issued2009-06-
dc.identifier.citationINORGANIC CHEMISTRY, v.48, no.11, pp.4634 - 4636-
dc.identifier.issn0020-1669-
dc.identifier.urihttp://hdl.handle.net/10203/18631-
dc.description.abstractA chiral metallocorrole complex, oxo[5-(4-bromophenyl)-10- (pentafluorophenyl)-15-(2-thianaphthyl)corrolato]chromium(V)(7), was prepared and serves as the first example of an ABC-metallocorrole; meso substituents are of different electron-withdrawing capacity. An adaptation of a multistep protocol (D. T. Gryko) was made, followed by an aerobic oxidation using Cr(CO)(6) (Z. Gross). The X-ray crystal structure reveals the two enantiomers of 7. Electron paramagnetic resonance spectroscopy (g(iso) = 1.99) and cyclic voltammetry of 7 provide comparative data to that of the A(3)[tris(pfp) cCr(V)O] complex.-
dc.description.sponsorshipsupport from KOSEF (Grant R01-2008-000-12388-0)en
dc.languageEnglish-
dc.language.isoen_USen
dc.publisherAMER CHEMICAL SOC-
dc.subjectCHROMIUM CORROLES-
dc.subjectEFFICIENT SYNTHESIS-
dc.subjectDIPYRROMETHANES-
dc.subjectPORPHYRIN-
dc.subjectFLUORESCENCE-
dc.subjectDIPYRRINS-
dc.subjectOXIDATION-
dc.subjectMANGANESE-
dc.subjectBEARING-
dc.titleA Chiral meso-ABC-Corrolatochromium(V) Complex-
dc.typeArticle-
dc.identifier.wosid000266428100015-
dc.identifier.scopusid2-s2.0-66249117966-
dc.type.rimsART-
dc.citation.volume48-
dc.citation.issue11-
dc.citation.beginningpage4634-
dc.citation.endingpage4636-
dc.citation.publicationnameINORGANIC CHEMISTRY-
dc.identifier.doi10.1021/ic900393v-
dc.embargo.liftdate9999-12-31-
dc.embargo.terms9999-12-31-
dc.contributor.localauthorChurchill, David G-
dc.contributor.nonIdAuthorEgorova, Olga A.-
dc.contributor.nonIdAuthorKhatua, Snehadrinarayan-
dc.contributor.nonIdAuthorHuh, Jung-Oh-
dc.type.journalArticleArticle-
dc.subject.keywordPlusCHROMIUM CORROLES-
dc.subject.keywordPlusEFFICIENT SYNTHESIS-
dc.subject.keywordPlusDIPYRROMETHANES-
dc.subject.keywordPlusPORPHYRIN-
dc.subject.keywordPlusFLUORESCENCE-
dc.subject.keywordPlusDIPYRRINS-
dc.subject.keywordPlusOXIDATION-
dc.subject.keywordPlusMANGANESE-
dc.subject.keywordPlusBEARING-
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