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College of Natural Sciences(자연과학대학)Dept. of Chemistry(화학과)CH-Journal Papers(저널논문)

A novel C-C bond formation by Baylis-Hillman type reaction mediated by SmI2: an effective approach to alpha-hydroxyalkylacrylamide synthesis

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dc.contributor.authorYoun, SWko
dc.contributor.authorPark, HSko
dc.contributor.authorKim, Yong Haeko
dc.date.accessioned2013-08-30-
dc.date.available2013-08-30-
dc.date.created2012-02-06-
dc.date.created2012-02-06-
dc.date.issued2000-07-
dc.identifier.citationCHEMICAL COMMUNICATIONS, pp.2005 - 2006-
dc.identifier.issn1359-7345-
dc.identifier.urihttp://hdl.handle.net/10203/176624-
dc.description.abstractalpha-Bromoacrylamides (1) reacted with aldehydes or ketones, in the presence of SmI2 at -78 degrees C in THF, within 5 min to produce Baylis-Hillman type reaction products (2) through an anionic process using vinylsamarium Grignard species in good yields (52-89%).-
dc.languageEnglish-
dc.publisherROYAL SOC CHEMISTRY-
dc.subjectLIGAND-ACCELERATED CATALYSIS-
dc.subjectSAMARIUM(II) IODIDE-
dc.subjectCARBONYL-COMPOUNDS-
dc.subjectASYMMETRIC-SYNTHESIS-
dc.subjectRATE ENHANCEMENT-
dc.subjectVINYL RADICALS-
dc.subjectFIRST-EXAMPLES-
dc.subjectDIIODIDE-
dc.subjectREAGENTS-
dc.subjectCYCLIZATION-
dc.titleA novel C-C bond formation by Baylis-Hillman type reaction mediated by SmI2: an effective approach to alpha-hydroxyalkylacrylamide synthesis-
dc.typeArticle-
dc.identifier.wosid000089790600011-
dc.type.rimsART-
dc.citation.beginningpage2005-
dc.citation.endingpage2006-
dc.citation.publicationnameCHEMICAL COMMUNICATIONS-
dc.identifier.doi10.1039/b006495p-
dc.contributor.nonIdAuthorYoun, SW-
dc.contributor.nonIdAuthorPark, HS-
dc.type.journalArticleArticle-
dc.subject.keywordPlusLIGAND-ACCELERATED CATALYSIS-
dc.subject.keywordPlusSAMARIUM(II) IODIDE-
dc.subject.keywordPlusCARBONYL-COMPOUNDS-
dc.subject.keywordPlusASYMMETRIC-SYNTHESIS-
dc.subject.keywordPlusRATE ENHANCEMENT-
dc.subject.keywordPlusVINYL RADICALS-
dc.subject.keywordPlusFIRST-EXAMPLES-
dc.subject.keywordPlusDIIODIDE-
dc.subject.keywordPlusREAGENTS-
dc.subject.keywordPlusCYCLIZATION-
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