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College of Natural Sciences(자연과학대학)Dept. of Chemistry(화학과)CH-Journal Papers(저널논문)

Copper-Mediated Transformation of Organosilanes to Nitriles with DMF and Ammonium Iodide

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dc.contributor.authorWang, Zhenko
dc.contributor.authorChang, Sukbokko
dc.date.accessioned2013-08-08T06:03:12Z-
dc.date.available2013-08-08T06:03:12Z-
dc.date.created2013-06-11-
dc.date.created2013-06-11-
dc.date.issued2013-04-
dc.identifier.citationORGANIC LETTERS, v.15, no.8, pp.1990 - 1993-
dc.identifier.issn1523-7060-
dc.identifier.urihttp://hdl.handle.net/10203/174818-
dc.description.abstractCyanation of aryl-, diaryldimethyl-, and styrylsilanes was developed for the first time under copper-mediated oxidative conditions using ammonium iodide and DMF as the combined source of nitrogen and carbon atom of the introduced cyano unit, respectively. The reaction was observed to proceed in a two-step process: initial conversion of organosilanes to their iodo intermediates and then cyanation. This method has a broad substrate scope with high functional group tolerance.-
dc.languageEnglish-
dc.publisherAMER CHEMICAL SOC-
dc.subjectPALLADIUM-CATALYZED CYANATION-
dc.subjectCROSS-COUPLING REACTIONS-
dc.subjectC-H BONDS-
dc.subjectARYL HALIDES-
dc.subjectCONVENIENT PROCEDURE-
dc.subjectSODIUM-HYDROXIDE-
dc.subjectAROMATIC HALIDES-
dc.subjectTRANSITION-METAL-
dc.subjectBORONIC ACIDS-
dc.subjectBROMIDES-
dc.titleCopper-Mediated Transformation of Organosilanes to Nitriles with DMF and Ammonium Iodide-
dc.typeArticle-
dc.identifier.wosid000318001400051-
dc.identifier.scopusid2-s2.0-84876579692-
dc.type.rimsART-
dc.citation.volume15-
dc.citation.issue8-
dc.citation.beginningpage1990-
dc.citation.endingpage1993-
dc.citation.publicationnameORGANIC LETTERS-
dc.identifier.doi10.1021/ol400659p-
dc.contributor.localauthorChang, Sukbok-
dc.contributor.nonIdAuthorWang, Zhen-
dc.type.journalArticleArticle-
dc.subject.keywordPlusPALLADIUM-CATALYZED CYANATION-
dc.subject.keywordPlusCROSS-COUPLING REACTIONS-
dc.subject.keywordPlusC-H BONDS-
dc.subject.keywordPlusARYL HALIDES-
dc.subject.keywordPlusCONVENIENT PROCEDURE-
dc.subject.keywordPlusSODIUM-HYDROXIDE-
dc.subject.keywordPlusAROMATIC HALIDES-
dc.subject.keywordPlusTRANSITION-METAL-
dc.subject.keywordPlusBORONIC ACIDS-
dc.subject.keywordPlusBROMIDES-
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