Friction and wear behavior of hot isostatic pressed Al2O3-TiC was experimentally examined. Pin-on-disk type friction and wear apparatus was designed and manufactured for the experiment. The experiments were conducted under unlubricated sliding motion in both low and high humidity for three kinds of sliding speed. Al2O3-TiC and bearing steel were used as counterface materials. Friction coefficient, wear rate, and surface roughness were measured. Wear surface and wear debris were observed through optical microscope and SEM and analyzed by EDAX. The results showed that the counterface materials, the sliding speed, and the moisture at the sliding surface have significant influence on the friction coefficient and wear rate of Al2O3-TiC.