The setting and hardening of concrete is accompanied with nonlinear temperature distribution caused by development of hydration heat of cement. In order to predict the exact temperature history in concrete structures it is required to examine thermal properties of concrete. In this study, the coefficient of air convection, which presents thermal transfer between surface of concrete and air, was experimentally investigated with variables such as velocity of wind, boiling and layer effects. Finally, the prediction model for equivalent coefficient of air convection was theoretically proposed. The coefficient of air convection in the proposed model increases with velocity of wind, and its dependance on wind velocity is varied with types of form. For determining the initial coefficient of air convection, boiling effects must be considered. The coefficient of air convection is affected by boundary layer with respect to the distance from the surface.