DC Field | Value | Language |
---|---|---|
dc.contributor.author | Lim, GI | ko |
dc.contributor.author | Lim, SM | ko |
dc.contributor.author | Kim, Sangkyu | ko |
dc.contributor.author | Choi, YS | ko |
dc.date.accessioned | 2009-12-08T01:21:58Z | - |
dc.date.available | 2009-12-08T01:21:58Z | - |
dc.date.created | 2012-02-06 | - |
dc.date.created | 2012-02-06 | - |
dc.date.issued | 1999-07 | - |
dc.identifier.citation | JOURNAL OF CHEMICAL PHYSICS, v.111, no.2, pp.456 - 459 | - |
dc.identifier.issn | 0021-9606 | - |
dc.identifier.uri | http://hdl.handle.net/10203/14348 | - |
dc.description.abstract | The fluorescence intensity ratios of (OClO)-Cl-37/(OClO)-Cl-35 excited to the (A) over tilde (2)A(2) state have been found to be much larger than that expected from the Cl-37/Cl-35 natural abundance ratio for several low-energy vibrational levels. For instance, the (OClO)-Cl-37/(OClO)-Cl-35 ratios are 1.67 and >10 for the (0,0,0) and (1,1,0) bands, respectively, which are 5 and 30 times larger than those expected from the natural abundance ratio. These unusual isotope effects are observed in a narrow energy region within similar to 1000 cm(-1) above the electronic origin. It is likely that the isotopomer-selective, near-resonant spin-orbit coupling of the low-energy vibrational levels of the (2)A(2) state with those of the (2)A(1) state, which provides a decay channel for the (2)A(2) state via spin-orbit coupling, is responsible for the unusual isotope effect. (C) 1999 American Institute of Physics. [S0021-9606(99)02126-1]. | - |
dc.description.sponsorship | Korean Science and Engineering Foundation Inha University Research Fund | en |
dc.language | English | - |
dc.language.iso | en_US | en |
dc.publisher | AMER INST PHYSICS | - |
dc.subject | CHLORINE DIOXIDE | - |
dc.subject | PHOTODISSOCIATION DYNAMICS | - |
dc.subject | STATE | - |
dc.subject | OCIO | - |
dc.subject | CLO2 | - |
dc.subject | SPECTROSCOPY | - |
dc.subject | TRANSITION | - |
dc.subject | NM | - |
dc.title | Unexpectedly large (OClO)-Cl-37/(OClO)-Cl-35 intensity ratios of the fluorescence from the low-energy vibrational levels of OClO ((A)over-tilde(2)A(2)) | - |
dc.type | Article | - |
dc.identifier.wosid | 000081067300004 | - |
dc.identifier.scopusid | 2-s2.0-0000254004 | - |
dc.type.rims | ART | - |
dc.citation.volume | 111 | - |
dc.citation.issue | 2 | - |
dc.citation.beginningpage | 456 | - |
dc.citation.endingpage | 459 | - |
dc.citation.publicationname | JOURNAL OF CHEMICAL PHYSICS | - |
dc.identifier.doi | 10.1063/1.479325 | - |
dc.embargo.liftdate | 9999-12-31 | - |
dc.embargo.terms | 9999-12-31 | - |
dc.contributor.localauthor | Kim, Sangkyu | - |
dc.contributor.nonIdAuthor | Lim, GI | - |
dc.contributor.nonIdAuthor | Lim, SM | - |
dc.contributor.nonIdAuthor | Choi, YS | - |
dc.type.journalArticle | Article | - |
dc.subject.keywordPlus | CHLORINE DIOXIDE | - |
dc.subject.keywordPlus | PHOTODISSOCIATION DYNAMICS | - |
dc.subject.keywordPlus | STATE | - |
dc.subject.keywordPlus | OCIO | - |
dc.subject.keywordPlus | CLO2 | - |
dc.subject.keywordPlus | SPECTROSCOPY | - |
dc.subject.keywordPlus | TRANSITION | - |
dc.subject.keywordPlus | NM | - |
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.