DC Field | Value | Language |
---|---|---|
dc.contributor.author | Cho, WK | ko |
dc.contributor.author | Lee, JK | ko |
dc.contributor.author | Kang, SM | ko |
dc.contributor.author | Chi, YS | ko |
dc.contributor.author | Lee, Hee-Seung | ko |
dc.contributor.author | Choi, Insung | ko |
dc.date.accessioned | 2009-11-20T08:45:31Z | - |
dc.date.available | 2009-11-20T08:45:31Z | - |
dc.date.created | 2012-02-06 | - |
dc.date.created | 2012-02-06 | - |
dc.date.issued | 2007 | - |
dc.identifier.citation | CHEMISTRY-A EUROPEAN JOURNAL, v.13, no.22, pp.6351 - 6358 | - |
dc.identifier.issn | 0947-6539 | - |
dc.identifier.uri | http://hdl.handle.net/10203/13032 | - |
dc.description.abstract | Gold had been considered to be an extremely inert metal, but recently it was found that nanometer-sized gold particles on metal-oxide supports acted as catalysts for simple organic reactions, such as oxidation and hydrogenation, even at or below room temperature. Herein, we report that gold nanoparticles (AuNPs) of zero oxidation state (Au-0) are catalytically active for a C-C bond-forming reaction, the cyanosilylation of aldehydes. ne AuNP-catalyzed cyanosilylation proceeded smoothly at room temperature with 0.2 wt% loading of AuNPs. The reactions of aromatic aldehydes were almost quantitative, except for benzaldehyde derivatives containing the electron-withdrawing NO2 group, and alpha,beta-unsaturated aromatic aldehydes were the most reactive substrates. The reactions also went smoothly for aliphatic aldehydes. Mechanistic studies indicated that the reactions proceeded both homogeneously and heterogeneously: homogeneous catalysis by leached gold species and heterogeneous catalysis by the adsorption of the reactants (aldehydes and trimethylsilyl cyanide) onto AuNPs. The ratio of homogeneous and heterogeneous catalysis was estimated to be approximate to 4:1. | - |
dc.language | English | - |
dc.language.iso | en_US | en |
dc.publisher | WILEY-V C H VERLAG GMBH | - |
dc.subject | ENHANCED RAMAN-SCATTERING | - |
dc.subject | SILVER NANOPARTICLE SURFACES | - |
dc.subject | SELF-ASSEMBLED MONOLAYERS | - |
dc.subject | C-BOND FORMATION | - |
dc.subject | ENANTIOSELECTIVE CYANOSILYLATION | - |
dc.subject | PHENYLBORONIC ACID | - |
dc.subject | PHASE OXIDATION | - |
dc.subject | METAL-COMPLEXES | - |
dc.subject | PRIMARY AMINES | - |
dc.subject | PLATINUM-GROUP | - |
dc.title | Gold-catalyzed cyanosilylation reaction: Homogeneous and heterogeneous pathways | - |
dc.type | Article | - |
dc.identifier.wosid | 000248558800007 | - |
dc.identifier.scopusid | 2-s2.0-34547566979 | - |
dc.type.rims | ART | - |
dc.citation.volume | 13 | - |
dc.citation.issue | 22 | - |
dc.citation.beginningpage | 6351 | - |
dc.citation.endingpage | 6358 | - |
dc.citation.publicationname | CHEMISTRY-A EUROPEAN JOURNAL | - |
dc.identifier.doi | 10.1002/chem.200601791 | - |
dc.embargo.liftdate | 9999-12-31 | - |
dc.embargo.terms | 9999-12-31 | - |
dc.contributor.localauthor | Lee, Hee-Seung | - |
dc.contributor.localauthor | Choi, Insung | - |
dc.contributor.nonIdAuthor | Cho, WK | - |
dc.contributor.nonIdAuthor | Lee, JK | - |
dc.contributor.nonIdAuthor | Kang, SM | - |
dc.contributor.nonIdAuthor | Chi, YS | - |
dc.type.journalArticle | Article | - |
dc.subject.keywordAuthor | aldehydes | - |
dc.subject.keywordAuthor | cyanosilylation | - |
dc.subject.keywordAuthor | gold | - |
dc.subject.keywordAuthor | heterogeneous catalysis | - |
dc.subject.keywordAuthor | homogeneous catalysis | - |
dc.subject.keywordPlus | ENHANCED RAMAN-SCATTERING | - |
dc.subject.keywordPlus | SILVER NANOPARTICLE SURFACES | - |
dc.subject.keywordPlus | SELF-ASSEMBLED MONOLAYERS | - |
dc.subject.keywordPlus | C-BOND FORMATION | - |
dc.subject.keywordPlus | ENANTIOSELECTIVE CYANOSILYLATION | - |
dc.subject.keywordPlus | PHENYLBORONIC ACID | - |
dc.subject.keywordPlus | PHASE OXIDATION | - |
dc.subject.keywordPlus | METAL-COMPLEXES | - |
dc.subject.keywordPlus | PRIMARY AMINES | - |
dc.subject.keywordPlus | PLATINUM-GROUP | - |
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