In the concrete structures exposed to environmental conditions at early ages, water movement occurs by moisture diffusion in the concrete, and self-desiccation of concrete is also occurred. Thus the internal relative humidity is changed from moisture diffusion and self-desiccation. Thus the internal relative humidity at each location in concrete includes the decrease by self-desiccation. Especially, for high-strength concrete the much unit cement content is used, so that the non-uniform relative humidity distribution is affected form self-desiccation at early ages. In this study, the internal relative humidity in concrete was measured at early ages, and the moisture diffusion component and self-desiccation component of total relative humidity were discussed.